石膏对硫铝酸盐水泥水化特性的影响  

Impact of Calcium Sulfate on Hydration Features of Calcium Sulfoaluminate Cement

作　　者：徐玲琳[1] 周向艺 李楠[1] 王培铭[1] 

机构地区：[1]同济大学先进土木工程材料教育部重点实验室,上海201804 [2]云南省建筑科学研究院,云南昆明650223

出　　处：《同济大学学报（自然科学版）》2017年第6期885-890,共6页Journal of Tongji University:Natural Science

基　　金：国家自然科学基金(51402216);国家重点研发计划(2016YFB0303503;2016YFC0700905);高性能土木工程材料国家重点实验室开放基金

摘　　要：研究了无水石膏及脱硫石膏对硫铝酸盐水泥抗压强度、干燥收缩率、早期水化放热及浆体组成的影响.结果表明:石膏能加速硫铝酸盐水泥的早期水化,低掺量(≤20%,质量分数)时1 d抗压强度提高,干燥收缩有所降低;随石膏掺量增加,3 d和28 d抗压强度先增后减;掺量过高时硬化浆体的后期强度甚至会倒缩;抗压强度与钙矾石生成量并无直接关联,与铝胶量成正相关.脱硫石膏可替代无水石膏配制出更优良的硫铝酸盐水泥,具有广阔前景.The impact of calcium sulfate （anhydrite and desulphurization gypsum） on the hydration of calcium sulfoaluminate （CSA） cement, such as compressive strength, drying shrinkage ratio, hydration heat of early stage and microstructure evolution, was measured. Results reveal that, the early hydration of CSA cement is accelerated by the addition of calcium sulfate, resulting in higher 1-day compressive strength and lower drying shrinkage once the dosage is less than 20% （mass ratio）. However, with the increasing amount of calcium sulfate, 3-day and 28-day strength is prominently decreased, and even the retraction of strength happens when doping with excessive calcium sulfate. Compressive strength has no direct correlations with ettringite amount, while it has positive correlation with the alumina gel amount. Additionally, to achieve CSA cement with better properties, it is very promising to replace anhydrite with desulphurization gypsum.

关 键 词：石膏 硫铝酸盐水泥 水化 钙矾石 铝胶 

分 类 号：TU528.41[建筑科学—建筑技术科学]