呋喃甲醛缩D-氨基葡萄糖Schiff碱及Cu(Ⅱ)配合物的合成与表征  

Synthesis and Characterization of Cu(Ⅱ) Complexes Of Schiff-Base Derived from D-Glucosamine Condensed With 2-Furaldehyde

作　　者：张孝[1] 

机构地区：[1]中南大学化学化工学院,湖南长沙410004

出　　处：《广东化工》2017年第11期115-117,共3页Guangdong Chemical Industry

摘　　要：在冰盐浴条件下,用醋酸钠调节p H=6~7,以呋喃甲醛和D-氨基葡萄糖盐酸盐为原料(n1︰n2=1︰1),用乙醇与乙醚的混合溶液为溶剂,合成了呋喃甲醛缩D-氨基葡萄糖Schiff碱及其铜(Ⅱ)配合物。通过IR、UV-Vis、摩尔电导率测定、熔点测定、差热-热重分析等手段对配合物进行了表征,并推断了配合物结构。The synthesis of Schiff base ligand of 2-Furaldehyde condensed with D-glucosamine hydrochloride and along with its copper （ II ） complexes, When n（D-glucosamine hydrochloride） ： n（2-Furaldehyde）=1 ： 1, under the ice salt bath condition, adjusts pH=6-7 with the CH3COONa, in methanol. These compounds were characterized by IR, UV-Vis, Molar conductance, melting point, DTA-TG and the metallic ion content of the complexes were measured. The possible composition and structures were initially discussed.

关 键 词：D-氨基葡萄糖盐酸盐 呋喃甲醛 SCHIFF碱 合成 

分 类 号：TQ[化学工程]