纳米压痕技术对比研究DNAN和TNT晶体的微观力学性能  

Comparative Study on Micromechanical Properties of DNAN and TNT Crystals by Nanoindentation

作　　者：朱一举 涂健[1] 常海[1] 苏鹏飞[1] 陈智群[1] 徐敏[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《火炸药学报》2017年第3期68-71,84,共5页Chinese Journal of Explosives & Propellants

基　　金：国防科工局技术基础计量项目(JSJL2014208A005)

摘　　要：通过溶剂挥发法制备了DNAN和TNT晶体;利用纳米压痕技术研究了DNAN和TNT晶体的微观力学性能(硬度和弹性模量);通过原位扫描探针成像技术(SPM)研究了DNAN和TNT晶体的压痕形貌随时间的变化差异。结果表明,DNAN晶体的平均硬度和弹性模量分别为7.82GPa和0.22GPa,TNT晶体的平均硬度和弹性模量分别为12.19GPa和0.48GPa,表明TNT抵抗变形的能力优于DNAN;随着压痕深度由118nm增至856nm,DNAN的硬度从0.61GPa降至0.22GPa;随着压痕深度由27nm增至481nm,TNT的硬度从2.9GPa降至0.48GPa,表明DNAN和TNT均存在尺寸效应。随着时间由0增至50.4min,DNAN的压痕深度由-270.99nm减至-44.28nm,TNT的压痕深度由-415.12nm减至-369.21nm,表明DNAN晶体比TNT晶体具有更明显的慢回弹性,DNAN具有更强的冲击能量吸收能力。The DNAN and TNT crystals were prepared by solvent evaporation method.The micromechanical properties(hardness and elastic modulus)of DNAN and TNT crystals were studied by nanoindentation.The difference of variation of indentation with time was investigated by in situ scanning probe microscopy(SPM).The results show that the average hardness and elastic modulus are 7.82 GPa and 0.22 GPa for DNAN and 12.19 GPa and 0.48 GPa for TNT,respectively,indicating that the ability of resistance to deformation of TNT is stronger than that of DNAN.With increasing the indentation depth from 118 nm to 856 nm,the hardness of DNAN reduces from 0.61 GPa to 0.22GPa;With increasing the indentation depth from 27 nm to 481 nm,the hardness of TNT reduces from 2.9 GPa to 0.48 GPa,revealing that DNAN and TNT have size-effect.With increasing the time from 0 to 50 min,the indentation depth reduces from -270.99 nm to -44.28 nm for DNAN and from -415.12 nm to -369.21 nm for TNT,showing that the elastic resilience of DNAN crystal has more obvious slow elastic resilience than that of TNT crystal,which means DNAN has stronger ability to absorb impact energy.

关 键 词：纳米压痕 微观力学性能 含能单晶 DNAN TNT 溶剂挥发法 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] TQ560[化学工程—炸药化工]