有机硫稀土配合物的应用研究进展  

The Research Development of the Applications of Rare Earth Coordination Compounds Based on the Organic Sulfur Ligands

作　　者：梁福永[1] 谢欣荣[1] 杨凯[1] 温和瑞[1] LIANG Fu-yong XIE Xin-rong YANG Kai WEN He-rui(School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China)

机构地区：[1]江西理工大学冶金与化学工程学院,江西赣州341000

出　　处：《稀土》2017年第3期115-127,共13页Chinese Rare Earths

基　　金：国家自然科学基金项目(21161008);江西省教育厅科技落地计划项目(GCJ2011-243)

摘　　要：有机硫稀土配合物是以有机硫软碱配体与稀土离子配位形成的一类化合物,由于有机硫稀土配合物具有的一些可能的特殊性能和应用,近年来有机硫稀土配合物的研究已成为稀土配位化学研究的重要领域之一。本文综述了二硫代(氨基)甲酸、二硫代磷酸、硫脲、硫醇等有机硫稀土配合物的合成、结构与性质的研究进展,系统综述了有机硫稀土配合物在纳米稀土硫化物制备、橡胶硫化、新型摩擦剂、生物抗菌剂、催化剂、单分子磁性、电致发光材料、镧系元素萃取分离等方面的潜在应用。The rare earth complexes are a family of compounds derived from organic sulfur ligands and lanthanide ions. Recently,the lanthanide complexes based on the organic sulfur ligands have attracted considerable interests due to their special properties and potential applications. The synthesis, structures and properties of rare earth complexes based on organic sulfur ligands, such as dithioearbamate, dithiophosphate, thiol, thiourea, and others were reviewed in this paper. It was introduced the applications in preparation of rare-earth sulfides nanoparticle, vulcanization, new abrasive antimicrobial agent, catalyst, SIMs, electro-luminescent materials,lanthanide extraction separtion and so on.

关 键 词：有机硫配体 稀土配合物 结构 性质 应用 

分 类 号：O641.4[理学—物理化学]