Comparison of Persulfate Activation and Fenton Reaction in Remediating an Organophosphorus Pesticides-Polluted Soil  

作　　者：ZHU Changyin ZHU Fengxiao WANG Fuwang GAO Juan FAN Guangping ZHOU Dongmei FANG Guodong 

机构地区：[1]Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences [2]University of Chinese Academy of Sciences [3]Suzhou Jianbang Environmental Remediation Co., Ltd. [4]China Construction Power and Environment Engineering Co., Ltd.

出　　处：《Pedosphere》2017年第3期465-474,共10页土壤圈（英文版）

基　　金：supported by the National Key Basic Research Program of China (No. 2013CB934303);the Environmental Protection Program of Jiangsu Province of China (No. 2015011);the Youth Innovation Promotion Association of Chinese Academy of Sciences (No. 2014270)

摘　　要：Organophosphorus pesticides （OPs） are one of the most regular pollutants and frequently detected in the contaminated sites, so developing an efficient method for the treatment of OPs is highly required. The aim of the present study was to compare the effectiveness of persulfate （PS） activation and Fenton reaction in remediating the soil polluted with OPs. The polluted soil used in this study was sampled from an abandoned insecticide factory in Nantong, Jiangsu Province of China, mainly containing chloropyrifos （CP） and 4-bromo-2-chlorophenol （BCP, the raw material of profenofos） with total concentration of about 30 000 mg kg- 1. The results showed that both BCP and CP were efficiently degraded by base activation of PS, and increasing the ratio of NaOH/PS enhanced CP degradation, but slightly decreased BCP degradation. The greatest degradation rates for CP and BCP were 92% and 97%, respectively, with 7.0 tool L-1 NaOH and 0.21 tool L-1 PS and a soil-to-liquid ratio of 1：1. Furthermore, ferrous iron activation of PS also degraded BCP efficiently, but only 60% of CP was degraded under the same reaction conditions. These results indicated that base activation of PS was more feasible than Fe2＋ activation and Fenton reaction in remediating the soil polluted with OPs. The high degradation rate for CP may be linked to the initial hydrolyzation of CP by base to 3,5,6-trichloro-2-pyridinol, which can be further rapidly degraded by free radicals generated from base activation of PS.Organophosphorus pesticides(OPs) are one of the most regular pollutants and frequently detected in the contaminated sites,so developing an efficient method for the treatment of OPs is highly required. The aim of the present study was to compare the effectiveness of persulfate(PS) activation and Fenton reaction in remediating the soil polluted with OPs. The polluted soil used in this study was sampled from an abandoned insecticide factory in Nantong, Jiangsu Province of China, mainly containing chloropyrifos(CP) and 4-bromo-2-chlorophenol(BCP, the raw material of profenofos) with total concentration of about 30 000 mg kg^(-1). The results showed that both BCP and CP were efficiently degraded by base activation of PS, and increasing the ratio of Na OH/PS enhanced CP degradation, but slightly decreased BCP degradation. The greatest degradation rates for CP and BCP were 92% and 97%, respectively,with 7.0 mol L^(-1) Na OH and 0.21 mol L^(-1) PS and a soil-to-liquid ratio of 1:1. Furthermore, ferrous iron activation of PS also degraded BCP efficiently, but only 60% of CP was degraded under the same reaction conditions. These results indicated that base activation of PS was more feasible than Fe^(2+) activation and Fenton reaction in remediating the soil polluted with OPs. The high degradation rate for CP may be linked to the initial hydrolyzation of CP by base to 3,5,6-trichloro-2-pyridinol, which can be further rapidly degraded by free radicals generated from base activation of PS.

关 键 词：base activation 4-bromo-2-chlorophenol chioropyritbs degradation rate terrous iron 

分 类 号：X53[环境科学与工程—环境工程] X592