AlCl_3-H_2O催化体系催化1-癸烯齐聚工艺研究  

Study on 1-Decene Oligomerization Catalyzed by Aluminum Chloride-Water Complex

作　　者：王玉龙[1] 高晗[1] 梁宇[1] 金书函 和树立[1] 姜艳峰 WANG Yulong GAO Han LIANG Yu JIN Shuhan HE Shuli JIANG Yanfeng(Daqing Chemical Research Center of PetroChina Petrochemical Research Institute, Daqing, Heilongjiang 163714)

机构地区：[1]石油化工研究院大庆化工研究中心,黑龙江大庆163714

出　　处：《精细石油化工进展》2017年第3期51-54,共4页Advances in Fine Petrochemicals

摘　　要：以1-癸烯为原料,采用AlCl_3-H_2O催化体系催化1-癸烯齐聚反应,考察催化剂体系中水与AlCl_3用量、AlCl_3粒度、反应温度、反应时间对聚α-烯烃合成油(PAO)收率及黏温性能的影响。结果表明:当原料中水含量为80μg/g,用原料质量分数3%的AlCl_3,其中AlCl_3粒度为180μm,反应温度40℃,反应时间3h,产品聚α-烯烃合成油收率达98%,黏度指数达150。AlCl3-H2O catalyst system was used to catalyze 1-decene oligomerization reaction, and the effects of water volume and AlCl3 amount in the catalyst system, the particle size of AlCl3 , the reaction temperature, and the reaction time on the yield and viscosity-temperature performance of poly-alpha-olefin （PAO） synthetic oil were studied. The results of study have shown that the yield of poly-alpha-olefin synthetic oil product reaches 98% and its viscosity index reaches 150 when the water content in the material is 80 μg/g, the amount of AlCl3 of the particle size of 180μm accounts for 3 % （ mass fraction） of the material, the reaction temperature is 40℃, and the reaction time is 3 h.

关 键 词：聚Α-烯烃 1-癸烯 催化体系 齐聚工艺 合成油 

分 类 号：TE626.3[石油与天然气工程—油气加工工程] TQ316.314[化学工程—高聚物工业]