含三苯胺基团席夫碱的合成及其光学性质研究  

Synthesis and optical properties of triphenylamine-contained Schiff bases

作　　者：朱美安[1] 马静[1] 鲁天琪 王坡[1] 金凤[1] 

机构地区：[1]阜阳师范学院化学与材料工程学院,安徽阜阳236037

出　　处：《阜阳师范学院学报（自然科学版）》2017年第2期31-36,共6页Journal of Fuyang Normal University(Natural Science)

基　　金：国家自然科学基金项目(21401024);新型光电功能材料研究创新团队(kytd201710);国家级大学生创新训练计划项目(201610371015)资助

摘　　要：以对(邻)苯二甲醛和4-胺基苯基二苯胺为原料,合成了两种含三苯胺基团的席夫碱化合物,两种化合物结构经红外光谱、元素分析、电喷雾质谱进行了表征。运用紫外-可见吸收光谱和荧光发射光谱研究了化合物的光学性质。结果表明直线型化合物1的紫外和荧光光谱和V型化合物2相比发生了较大程度的红移。Two triphenylamine-contained Schiff bases were obtained by reaction of p-phthalaldehyde（o-phthalaldehyde） and 4-aminophenyl diphenylamine. The structures were characterized by IR, elemental analysis and ESI-MS. The optical proper- ties were studied by UV absorption spectra and fluorescence spectra. The results showed that the absorption and fluorescence spectra of 1 exhibit obvious trend of red-shift compared with those of 2.

关 键 词：光学性质 表征 三苯胺 席夫碱 

分 类 号：O626.23[理学—有机化学]