碱和盐对十二烷基硫酸钠/正戊醇-环己烷-水拟三元体系相图影响  

Influence of Alkali and Salt on Phase Diagram of Sodium Dodecyl Sulfate/n-Pentanol-Cyclohexane-Water Pseudo Ternary Systems

作　　者：朱艳[1] 原光[1] 原帅[1,2] 陈少杰[1] 姚卫琴[1] 田龙昭[1] 秦帆[1] 刘林梅[1] 

机构地区：[1]西安工程大学环境与化工学院,西安710048 [2]浙江大学材料科学与工程学系

出　　处：《应用化学》2017年第7期833-838,共6页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(50873081)资助项目~~

摘　　要：拟三元相图的研究可为获得制备纳米材料的微乳液提供理论依据。本文首先通过实验绘制了45℃下十二烷基硫酸钠(SDS)/正戊醇-环己烷-水溶液体系的拟三元相图,并用电导法进行了验证,说明电导的测定结果与相图吻合的很好。其次,绘制了45℃及65℃下,SDS/正戊醇-环己烷-水、SDS/正戊醇-环己烷-硝酸锌水溶液和SDS/正戊醇-环己烷-氢氧化钠水溶液体系的拟三元相图并对6个相图进行了比较,研究了碱(NaOH)和盐(Zn(NO_3)_2)对SDS/正戊醇-环己烷-水拟三元体系相图影响。结果表明,硝酸锌及碱的加入使SDS/正戊醇-环己烷-水拟三元相图水包油(O/W)和油包水(W/O)区域明显的缩小。45℃时,SDS/正戊醇-环己烷-氢氧化钠水溶液体系的拟三元相图中的O/W区域甚至消失;65℃时,O/W和W/O区域均存在,且3个相图的W/O和O/W区域有重叠区。在此基础上,确定了制备纳米Zn O的微乳液的条件,即SDS/正戊醇-环己烷-硝酸锌水溶液和SDS/正戊醇-环己烷-氢氧化钠水溶液体系的拟三元相图中W/O区域的重叠区(各相图中的Ⅱ区)。制备的纳米氧化锌为多晶结构,平均粒径为80 nm。An important application of psudo ternary phase diagrams is to obtain microemulsion for nano material preparation. Therefore, psudo ternary phase diagrams of sodium dodeeyl sulfate（ SDS）/n-CsHu OH- cyclohexane-water at 45℃ and its conductivity were studied. Pseudo ternary phase diagrams agree well with conductivity measurement. Then psudo ternary phase diagrams of SDS/n-CsH1OH-cyclohexane-water, SDS/ n-C5 H11 OH-cyclohexane-Zn （ NO3 ） 2, SDS/n-C5 H110H-cyclohexane-NaOH at 45℃ and 65 ℃ were measured and compared. The influence of alkali NaOH and salt Zn（NO3 ）2 on peudo ternary phase diagrams was discussed. The result shows that oil-in-water（O/W） and water-in-oil（W/O） microemulsion areas are smaller after （Zn（NO3）2） or （NaOH） was added into SDS/n-CsHI1OH- cyclohexane-water system. The O/W microemulsion areas disappeared in SDS/n-CsH11OH-cyclohexane-NaOH peudo ternary phase diagrams at 45℃. There are still 5 areas in psudo ternary phase diagrams and smaller O/W and W/O microemulsion areas after NaOH or Zn（NO3）2 was added in SDS/cyclohexane-water system at 65℃. These study results were applied in the preparation nano ZnO particle in microemulsion system. Tansimission electron microscopy and X-ray diffraction studies show that the sample preparaed by the guidance of psudo ternary phase diagrams is nano ZnO particle.

关 键 词：拟三元相图 纳米粒子 油包水微乳液 碱 盐 

分 类 号：O642[理学—物理化学]