基于氟硼二吡咯的共轭聚合物研究进展  

Research Progress on BODIPY-Based Conjugated Polymers

作　　者：张昊霖 李拓[1] 陈志坚[1] 

机构地区：[1]天津大学化工学院,天津300072

出　　处：《化学工业与工程》2017年第4期11-17,95,共8页Chemical Industry and Engineering

摘　　要：氟硼二吡咯(BODIPY)类功能染料因具有良好的光子及电子性质已经得到广泛的应用,对其共轭聚合物的研究则在近年受到广泛关注。与BODIPY单体相比,BODIPY的共轭聚合物具有更窄的带隙、吸收光谱的红移及更强的电子传导能力。BODIPY共轭聚合物在有机半导体材料及有机太阳能电池等方面具有广泛的应用前景。总结了BODIPY共轭聚合物的制备方法、结构与性质的关系以及应用等方面,提出了BODIPY共轭聚合物设计合成策略及未来的发展趋势。Boron-Dipyrromethene （BODIPY） dyes have been widely applied due to their outstanding opti- cal and electronic properties. The research on BODIPY-based conjugated polymers has attracted consider- able attention in recent years. In comparison with their monomers, BODIPY-based conjugated polymers display lower band gap, red-shifted absorption maximum, and higher charge carrier mobilities. Accord- ingly, BODIPY-based conjugated polymers have prospect applications in organic semiconducting materials and organic solar ceils. In this paper, the preparation, structure-property relationships, and applications of BODIPY-based conjugated polymers were reviewed. Furthermore, the rational design strategies as well as the future development of BODIPY-based conjugated polymers were discussed.

关 键 词：氟硼二吡咯 共轭聚合物 带隙 电化学聚合 

分 类 号：TQ448.21[化学工程—化学肥料工业]