Recent advances in heterogeneous catalytic conversion of glucose to 5-hydroxymethylfurfural via green routes  

作　　者：Jianjian Wang Jinxu Xi Qineng Xia Xiaohui Liu Yanqin Wang 

机构地区：[1]Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology [2]Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology

出　　处：《Science China Chemistry》2017年第7期870-886,共17页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(91545103,21273071,21403065);the Commission of Science and Technology of Shanghai Municipality(10dz2220500)

摘　　要：With concerns of diminishing fossil fuel reserves and environmental deterioration, great efforts have been made to explore novel approaches of efficiently utilizing bio-renewable feedstocks to produce chemicals and fuels. 5-Hydroxymethylfurfural(HMF),generated from dehydration of six-carbon ketose, is regarded as a primary and versatile renewable building block to realize the goal of production of these high valued products from renewable biomass resources transformation. In this review, we summarize the recent advances via green routes in the heterogeneous reaction system for the catalytic production of HMF from glucose conversion, and emphasize reaction pathways of these reaction approaches based on the fundamental mechanistic chemistry as well as highlight the challenges(such as separation and purification of products, reusing and regeneration of catalyst, recycling solvent) in this field.With concerns of diminishing fossil fuel reserves and environmental deterioration, great efforts have been made to explore novel approaches of efficiently utilizing bio-renewable feedstocks to produce chemicals and fuels. 5-Hydroxymethylfurfural（HMF）,generated from dehydration of six-carbon ketose, is regarded as a primary and versatile renewable building block to realize the goal of production of these high valued products from renewable biomass resources transformation. In this review, we summarize the recent advances via green routes in the heterogeneous reaction system for the catalytic production of HMF from glucose conversion, and emphasize reaction pathways of these reaction approaches based on the fundamental mechanistic chemistry as well as highlight the challenges（such as separation and purification of products, reusing and regeneration of catalyst, recycling solvent） in this field.

关 键 词：5-hydroxymethylfurfural glucose heterogeneous catalysis green route 

分 类 号：O626.11[理学—有机化学]