Solubility and metastable zone width measurement of 3,4-bis (3-nitrofurazan-4-yl) furoxan (DNTF) in ethanol + water  

作　　者：Lizhen Chen Liang Song Guanchao Lan Jianlong Wang 

机构地区：[1]School of Chemical and Environmental Engineering,North University of China

出　　处：《Chinese Journal of Chemical Engineering》2017年第5期646-651,共6页中国化学工程学报（英文版）

摘　　要：The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan(DNTF) in ethanol + water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width(MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol + water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol + water was calculated by the relationship between the cooling rate and the MSZW.The solubility and supersolubility of 3,4-bis（3-nitrofurazan-4-yl）furoxan（DNTF） in ethanol ＋ water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width（MSZW）. The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol ＋ water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol ＋ water was calculated by the relationship between the cooling rate and the MSZW.

关 键 词：3 4-Bis（3-nitrofurazan-4-yl）furoxan SOLUBILITY Metastable zone width Apparent nucleation order 

分 类 号：TQ560.72[化学工程—炸药化工]