PbSe量子点硅酸盐玻璃光纤的制备及光纤光致荧光光谱特性  

Preparation of PbSe-Quantum-Dot-Doped-Silicate Glass Fiber and the Fiber Photoluminescence Spectrum

作　　者：程成[1,2] 席子扬 姚建华[2] 

机构地区：[1]浙江工业大学光电子智能化技术研究所,杭州310023 [2]浙江省高端激光制造装备协同创新中心,杭州310014

出　　处：《光子学报》2017年第6期61-67,共7页Acta Photonica Sinica

基　　金：国家自然科学基金(Nos.61274124;61474100)资助~~

摘　　要：对钠硼铝硅酸盐玻璃熔体进行拉丝,再经过退火热处理,制备得到光纤直径80~130μm的PbSe量子点玻璃裸光纤.透射电镜分析发现光纤中PbSe量子点的晶粒尺寸为4.2~5.5nm,掺杂体积比约1%.对量子点光纤的柔性进行了初步测试.以980nm泵浦激光作为激励源,用荧光光谱仪观测了量子点光纤的荧光发射谱.结果表明:合适的量子点光纤的退火条件跟块玻璃不同.当退火温度为500~600℃、热处理时间为5~10h时,观测到量子点光纤有强烈的荧光辐射,峰值波长位于1 300~1 450nm,半高全宽达200~330nm.光纤最佳退火温度为600℃、时间7.5h.本文得到的量子点玻璃光纤可进一步制备成玻璃基底的量子点光纤型增益器件光纤放大器、光纤激光器等.PbSe quantum dot doped bare-optical fibers are prepared in laboratory by drawing sodiumaluminum-borosilicate-silicate-glass fusant and annealing heat treatment.The fibers are in the diameter of 80~130μm.Transmission-electron microscope measurement shows that the prepared PbSe quantum dot in the fibers are in the diameter of 4.2~5.5nm and with the doped volume ratio of 1%.The flexibility of Pbse quantum dot doped fibers is tested initially.The photoluminescence spectra of fibers are measured upon 980-nm pump by a fluorescence spectrometer.There is evidence to show that the available annealing condition of PbSe quantum dot fibers is different from PbSe quantum dot dopedbulk glass.When the annealing temperature is within 500~600℃and the annealing time spans 5~10h,the PbSe quantum dot fiber shows strongest photoluminescence emission,peaking wavelength ranging 1300~1 450 nm and full width at half maximum coming to 200~330nm.The optimum annealing temperature and time are 600 ℃ and 7.5h,respectively.The PbSe quantum dot fibers obtained in this paper can be used to format PbSe-quantum-dot-doped-fiber gain devices based on glass（such as fiber amplifiers and fiber lasers）in the future.

关 键 词：PbSe量子点 量子点光纤 熔融拉丝 退火热处理 光致荧光光谱 

分 类 号：O433.4[机械工程—光学工程]