反应量热仪在线探究硝酸硝解乌洛托品反应过程  

The Exploration of the Reaction Process of Nitrifying Methenamine by Reaction Calorimeter

作　　者：高宇鹏[1] 陈丽珍[1] 王建龙[1] 朱艾鹏 张天贝 

机构地区：[1]中北大学化工与环境学院,太原030051

出　　处：《科学技术与工程》2017年第17期288-291,共4页Science Technology and Engineering

基　　金：国防产品创新项目资助

摘　　要：采用反应量热仪(Easy Max102)在线监测硝酸直接硝解乌洛托品的反应过程。研究结果表明,硝化温度越低,硝化过程放热量越低;加料时间越短,放热速率越大;成熟温度越高,绝热温升越高。不同反应条件下的热危险严重度都属于中级。综合经济与安全因素考虑,硝化温度为0℃,加料时间为20 min,成熟温度为30℃时为最佳工艺。The reaction calorimeter（EasyMax102） was used to observe the reaction process of nitrifying methenamine. The research shows that the exothermal of nitrification fluctuates accordantly with the nitrification temperature while the total exothermal is the same. The exothermal of nitrification fluctuates oppositely with the feeding time. The adiabatic temperature rise fluctuates accordantly with the mature temperature. All the results indicate that the thermal hazard is middle. Through the study of thermal hazard,it indicates the optimum preparation is that the nitrification temperature is 0 ℃,the feeding time is 20 min,the mature temperature is 30 ℃.

关 键 词：反应量热 硝酸 乌洛托品 反应过程 

分 类 号：TQ564[化学工程—炸药化工] TJ55[兵器科学与技术—军事化学与烟火技术]