电羧化：一种固定CO2制备有机羧酸的有效途径  

Electrocarboxylation:An Effective Process for Fixation of CO_2 into Organic Carboxylic Acids

作　　者：王欢[1] 陆嘉星[1] WANG Huan LU Jia-xing(Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, Chin)

机构地区：[1]华东师范大学化学与分子工程学院,上海市绿色化学与化工过程绿色化重点实验室,上海200062

出　　处：《电化学》2017年第3期250-261,共12页Journal of Electrochemistry

基　　金：国家自然科学基金项目(No.20573037,No.20973065,No.21373090,No.21473060,No.21673078)资助

摘　　要：温室气体CO_2的绿色高效转化利用是当前的研究热点.其中,有机物的电化学羧化反应是CO_2利用的有效途径.温和条件(常温常压)下,有机底物电还原生成的碳负离子可以捕获体系中的CO_2,进而合成具有高附加值的有机羧酸类化合物.本文重点介绍了作者课题组在电羧化反应方面的研究进展,包括各类电活性基团物质的电羧化反应以及不对称电羧化反应.Conversion and utilization of greenhouse gas carbon dioxide （CO2） have become more and more significant to the sustainable development of the global economy. Among them, electrocarboxylation of organic substratesis an effective process. Under mild conditions such as ambient temperature and pressure, carbocations generated by electroreduction of organic substrates can react with CO2 into corresponding carboxylic acids. This paper introduces the recent progress of our group in electrochemical carboxylation, including electrocarboxylation of varies active organic substrates and asymmetric electrocarboxylation.

关 键 词：电羧化 二氧化碳 有机电合成 

分 类 号：O622.5[理学—有机化学]