电化学条件下α-C-H键的官能团化的研究进展  

Research Progresses of α-C-H Bond Functionalizations under Electrochemical Conditions

作　　者：钱朋 毕美香 王玉康[1] 查正根[1] 汪志勇[1] QIAN Peng BI Mei-xiang WANG Yu-kang ZHA Zheng-gen WANG Zhi-yong(Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, P. R. Chin)

机构地区：[1]合肥微尺度国家实验室,中国科学技术大学化学与材料科学学院.合肥230026

出　　处：《电化学》2017年第3期262-275,共14页Journal of Electrochemistry

基　　金：国家自然科学基金项目(No.21272222,No.21172205,No.21432009,No.21472177,No.21672200)资助

摘　　要：近年来,有机电化学合成已经成为有机合成化学中构造碳碳及碳杂键的重要方法.本文主要综述了目前电化学合成的主要研究方向,着重介绍了作者课题组在电化学合成中利用碘自由基促进苯乙酮α-C-H键的官能团化所取得的研究进展,为绿色有机合成的发展提供了新的思路和方向.Recently, organic electrochemical synthesis has emerged as the most important and attractive method to construct carbon-carbon bond and carbon-heteroatom bonds in organic synthetic chemistry. This review mainly summarizes the electrochemi- cal syntheses at present, especially focused on the recent progresses in our research group using an iodine radical as a mediator to promote a-C-H bond fimctionalization. The organic electrosynthesis provides an alternative approach and a new research direction in the development of green organic synthesis.

关 键 词：有机电合成 碘自由基 C-H官能团化 绿色合成 

分 类 号：O621.38[理学—有机化学]