1,2,4-噁二唑类含能化合物研究进展  

Review on Energetic Compounds Based on 1,2,4-Oxadiazoles

作　　者：黄晓川[1] 王子俊[1] 郭涛[1] 秦明娜[1] 刘敏[1] 邱少君[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《含能材料》2017年第7期603-611,共9页Chinese Journal of Energetic Materials

摘　　要：1,2,4-噁二唑类含能化合物是近年来逐渐发展起来的一类新型含能材料,具有高密度、高氧平衡以及不敏感的特点。综述了关于单-1,2,4-噁二唑类、偶氮基-1,2,4-噁二唑类以及联-1,2,4-噁二唑类等三十余种含能化合物的最新合成研究成果,对部分化合物的性能进行了阐述,并结合1,2,4-噁二唑类含能化合物的性能特点,指出基于1,2,4-噁二唑环结构发展新型无卤氧化剂是较具潜力的发展方向。1 ,2,4-Oxadiazoles are a new class of energetic materials, which have the features of high density, high oxygen balance and insensitivity. In this paper, the latest organic synthesis achievements of more than 30 oxadiazole energetic compounds base on mono-1,2,4-oxadiazoles, azo-1,2,4-oxadiazoles and bis-1,2,4-oxadiazoles were reviewed, and their performances were also in- troduced in detail. 1.2,4-oxadiazoles would be new choice as chlorine-free oxidizers due to its advantages.

关 键 词：1 2 4-噁二唑 有机合成 含能材料 无卤氧化剂 研究进展 

分 类 号：TQ560.1[化学工程—炸药化工]