H_2等离子体制备免焙烧Ce改性的MoP加氢脱硫催化剂  

Preparation of Non-calcinated Ce Promoted Molybdenum Phosphide Hydrodesulfurization Catalyst by H_2 Plasma Reduction

作　　者：王伟[1,2] 遇治权[1] 李翔[1,3] 王安杰[1,3] 亓伟[2] 

机构地区：[1]大连理工大学精细化工国家重点实验室,辽宁大连116024 [2]银川能源学院,宁夏银川750105 [3]辽宁省省级高校石油化工技术与装备重点实验室,辽宁大连116024

出　　处：《石油学报（石油加工）》2017年第4期633-638,共6页Acta Petrolei Sinica(Petroleum Processing Section)

基　　金：国家自然科学基金项目(20973030;21073022;21173033);宁夏教育厅优秀青年培育基金项目(NGY201520)资助

摘　　要：采用免焙烧法制备催化剂前驱体,用H_2等离子体还原制备免焙烧的MoP(NC-MoP)催化剂和Ce改性的MoP(Ce-MoP(n))催化剂。对制备的催化剂进行XRD和N_2物理吸附表征,并用质量分数为0.8%的二苯并噻吩/十氢萘(DBT)溶液来考察催化剂的加氢脱硫(HDS)反应活性。与焙烧的MoP(C-MoP)催化剂相比,NC-MoP具有较小的颗粒尺寸和较大的比表面积,从而具有较高的DBT加氢脱硫反应活性;引入Ce后,催化剂的颗粒尺寸降低,比表面积增加,反应活性提高;Ce含量较低时,助催化效果随着Ce含量的增加而增强,Ce-MoP(0.3)具有最高的反应活性。Non-calcinated MoP （NC-MoP） and Ce promoted MoP （Ce-MoP（n）） catalysts were prepared by a non-calcination procedure, in which the precursors were directly converted to the active phosphide phase using the H2 plasma reduction （PR） method. The morphologies of the catalysts were characterized by XRD and N2 physical adsorption, and the hydrodesulfurization （HDS） performances were studied with a model fuel containing 0.8% （ mass fraction）dibenzothiophene （DBT） in decalin. Compared with the calcinated MoP （C-MoP） , NC-MoP possessed smaller particle size and larger specific surface area, leading to higher HDS activity. The introduction of Ce promoted the HDS activity, caused by the decrease of the particle size. At lower content of Ce, the promotion effect increased with the increase of Ce content, and Ce-MoP （0. 3） expressed the highest HDS performance.

关 键 词：磷化钼 加氢脱硫(HDS) 铈 改性 H2等离子体 免焙烧 

分 类 号：TE624.9[石油与天然气工程—油气加工工程]