Preparation of Chlorinated Poly(propylene carbonate) and Its Distinguished Properties  

作　　者：Xi-hua Cui Jing Jin Jie Cui 赵桂艳 姜伟 

机构地区：[1]State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [2]University of Science and Technology of China, Hefei 230026, China

出　　处：《Chinese Journal of Polymer Science》2017年第9期1086-1096,共11页高分子科学（英文版）

基　　金：This work was financially supported by the National Natural Science Foundation of China(No.51673195).

摘　　要：Poly（propylene carbonate） （PPC）, the copolymerization product of carbon dioxide and propylene oxide, was chlorinated for the first time in our laboratory. Nuclear magnetic resonance （NMR） spectroscopy and ion chromatography test showed that chlorine atoms were successfully introduced onto the polymer chains of PPC. We named this newborn polymer material as chlorinated poly（propylene carbonate） （CPPC）. It is worth noting that the reaction conditions of the chlorination of PPC were quite mild, which could be easily and simply realized at industrial level. What is more important is that CPPC possessed many more distinguished properties in solubility, wettability, adhesiveness, and gas barrier compared with PPC. For example, the bonding strength of CPPC as thermal adhesive is nearly four times higher than that of PPC for wood, stainless steel and glass. The oxygen permeability coefficient of CPPC exhibits a decrease of 33% compared with that of PPC. Moreover, CPPC is quite stable in air, whereas it could be well biodegraded in soil compared with PPC. These results indicated that CPPC could be widely used in the fields of coating, adhesive, barrier materials and so on, which could greatly promote the development of PPC industry.Poly（propylene carbonate） （PPC）, the copolymerization product of carbon dioxide and propylene oxide, was chlorinated for the first time in our laboratory. Nuclear magnetic resonance （NMR） spectroscopy and ion chromatography test showed that chlorine atoms were successfully introduced onto the polymer chains of PPC. We named this newborn polymer material as chlorinated poly（propylene carbonate） （CPPC）. It is worth noting that the reaction conditions of the chlorination of PPC were quite mild, which could be easily and simply realized at industrial level. What is more important is that CPPC possessed many more distinguished properties in solubility, wettability, adhesiveness, and gas barrier compared with PPC. For example, the bonding strength of CPPC as thermal adhesive is nearly four times higher than that of PPC for wood, stainless steel and glass. The oxygen permeability coefficient of CPPC exhibits a decrease of 33% compared with that of PPC. Moreover, CPPC is quite stable in air, whereas it could be well biodegraded in soil compared with PPC. These results indicated that CPPC could be widely used in the fields of coating, adhesive, barrier materials and so on, which could greatly promote the development of PPC industry.

关 键 词：Poly（propylene carbonate） CHLORINATION BIODEGRADABILITY ADHESIVE Gas barrier 

分 类 号：O633.14[理学—高分子化学]