The impacts of stress on the chemical structure of coals:a mini-review based on the recent development of mechanochemistry  

作　　者：Quanlin Hou Yuzhen Han Jin Wang Yijing Dong Jienan Pan 

机构地区：[1]Key Laboratory of Computational Geodynamics,CAS,College of Earth Science,University of Chinese Academy of Sciences [2]Key Laboratory of Earth and Planetary Physics,Institute of Geology and Geophysics,Chinese Academy of Sciences [3]School of Resource & Environment,Henan Polytechnic University

出　　处：《Science Bulletin》2017年第13期965-970,共6页科学通报（英文版）

基　　金：supported by the National Key Research and Development Program of China(2016YFC0600401);the National Natural Science Foundation of China(41030422)

摘　　要：The chemical structure evolution of coal,which is important for understanding coalification and the accompanying volatile and possible oil generation,is generally thought to be influenced by temperature,time and confining pressure.Though evidence concerning the impacts of stress on the chemical structure has accumulated for many years and some hypotheses have been proposed,the mechanism remains controversial.Recent years have seen a breakthrough in mechanochemistry,which proves that stress can act on the molecule directly to initiate or accelerate reactions by deforming the chemical bonds.The progress in mechanochemistry gives researchers incentive to consider how stress works on the chemical structure of coals.Preliminary quantum chemical calculations have been performed on the macromolecule of anthracite to explain the mechanism of gas generation during the deformation experiments at low temperatures.This paper briefly reviews the evidence regarding the impacts of stress on the chemical structure of coals and introduces the recent achievements in the mechanism research.To further investigate this problem,more work should be undertaken by researchers from both geology and quantum chemistry fields.The chemical structure evolution of coal, which is important for understanding coalification and the accompanying volatile and possible oil generation, is generally thought to be influenced by temperature, time and confining pressure. Though evidence concerning the impacts of stress on the chemical structure has accumulated for many years and some hypotheses have been proposed, the mechanism remains con- troversial. Recent years have seen a breakthrough in mechanochemistry, which proves that stress can act on the molecule directly to initiate or accelerate reactions by deforming the chemical bonds. The progress in mechanochemistry gives researchers incentive to consider how stress works on the chemical structure of coals. Preliminary quantum chemical calculations have been performed on the macromolecule of anthracite to explain the mechanism of gas generation during the deformation experiments at low tem- peratures. This paper briefly reviews the evidence regarding the impacts of stress on the chemical struc- ture of coals and introduces the recent achievements in the mechanism research. To further investigate this problem, more work should be undertaken by researchers from both geology and quantum chem- istry fields.

关 键 词：CoalStressChemical structureMechanochemistryQuantum chemical calculation 

分 类 号：TQ530[化学工程—煤化学工程]