溴化二甲基溴化锍催化合成二呋喃基芳基甲烷类化合物  

Synthesis of Difurylarylmethanes Catalyzed by Bromodimethylsulfonium Bromide

作　　者：刘巨艳[1] 黄海静[1] 焦德全[1] Liu Juyan Huang Haijing Jiao Dequan(Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 30038)

机构地区：[1]天津师范大学化学学院天津市功能分子结构与性能重点实验室无机-有机杂化功能材料化学教育部重点实验室,天津300387

出　　处：《有机化学》2017年第7期1808-1813,共6页Chinese Journal of Organic Chemistry

基　　金：天津市自然科学基金(No.12JCZDJC34300)资助项目~~

摘　　要：室温无溶剂的条件下,以溴化二甲基溴化锍(BDMS)为催化剂,以2-甲基呋喃和芳香醛为原料,能高收率地合成一系列二呋喃基芳基甲烷类化合物.所有化合物结构通过~1H NMR、^(13)C NMR表征确定.A series of difurylarylmethanes were prepared in high yields by condensation of 2-methylfuran with aromatic aldehydes in the presence of bromodimethylsufonium bromide（BMDS） at room temperature under solvent-free conditions. All products were characterized by 1H NMR and 13C NMR spectra.

关 键 词：溴化二甲基溴化锍(BDMS) 二呋喃基芳基甲烷 合成 

分 类 号：O621.251[理学—有机化学]