Recent advances in visible-light-driven organic reactions  

作　　者：Qiang Liu Li-Zhu Wu 

机构地区：[1]State Key Laboratory of Applied Organic Chemistry,Lanzhou University [2]Key Laboratory of Photochemical Conversion and Optoelectronic Materials,Technical Institute of Physics and Chemistry,Chinese Academy of Sciences

出　　处：《National Science Review》2017年第3期359-380,共22页国家科学评论（英文版）

基　　金：financial support from the Ministry of Science and Technology of China(2013CB834804,2013CB834505and 2014CB239402);the National Natural Science Foundation of China(21572090,21390404 and 91427303);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17030200);the Chinese Academy of Sciences

摘　　要：In recent years, visible-light-driven organic reactions have been experiencing a significant renaissance in response to topical interest in environmentally friendly green chemical synthesis. The transformations using inexpensive, readily available visible-light sources have come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In this review, we focus on recent advances in the development of visible-light-driven organic reactions, including aerobic oxidation, hydrogen-evolution reactions, energy-transfer reactions and asymmetric reactions. These key research topics represent a promising strategy towards the development of practical, scalable industrial processes with great environmental benefits.In recent years, visible-light-driven organic reactions have been experiencing a significant renaissance in response to topical interest in environmentally friendly green chemical synthesis. The transformations using inexpensive, readily available visible-light sources have come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In this review, we focus on recent advances in the development of visible-light-driven organic reactions, including aerobic oxidation, hydrogen-evolution reactions, energy-transfer reactions and asymmetric reactions. These key research topics represent a promising strategy towards the development of practical, scalable industrial processes with great environmental benefits.

关 键 词：visible light CATALYSIS synthesis PHOTOCATALYST aerobic oxidation hydrogen evolution energy transfer asymmetric photoreaction 

分 类 号：O621.251[理学—有机化学] O644.1[理学—化学]