Electronic structure and photoluminescence property of a novel white emission phosphor Na_3MgZr(PO_4)_3:Dy^(3+) for warm white light emitting diodes  

作　　者：朱革 李卓为 王闯 周发光 温艳 辛双宇 

机构地区：[1]College of New Energy,Bohai University [2]School of Physics and Optoelectronic Engineering,Nanjing University of Information Science and Technology

出　　处：《Chinese Physics B》2017年第9期449-453,共5页中国物理B（英文版）

基　　金：Project supported by the Doctoral Research Fund of Liaoning Province,China(Grant No.201601351);the National Natural Science Foundation of China(Grant No.51502142);the General Program of Natural Science Foundation of the Jiangsu Provincial Higher Education Institutions,China(Grant No.15KJB430021)

摘　　要：To explore suitable single-phase white emission phosphors for warm white light emitting diodes, a series of novel phosphors Na3MgZr（PO4）3：xDy^3＋（0 ≤ x ≤ 0.03） is prepared, and their phase purities as well as photoluminescence properties are discussed in depth via x-ray diffraction structure refinement and photoluminescence spectrum measurement.The electronic structure properties of the Na3MgZr（PO4）3host are calculated. The results reveal that Na3MgZr（PO4）3 possesses a direct band gap with a band gap value of 4.917 eV. The obtained Na3MgZr（PO4）3：Dy^3＋ phosphors are all well crystallized in trigonal structure with space group Rc, which has strong absorption around 365 nm and can generate warm white light emissions peaking at 487, 576, and 673 nm upon ultraviolet excitation, which are attributed to the transitions from -4F9/2 to ^6H15/2,^6H13/2, and ^6H11/2 of Dy^3＋ ions, respectively. The optimal doping content, critical distance, decay time, and Commission International de L＇Eclairage（CIE） chromaticity coordinates are investigated in Dy^3＋ ion-doped Na3MgZr（PO4）3. The thermal quenching analysis shows that Na3MgZr（PO4）3：Dy^3＋ has a good thermal stability, and the thermal activation energy is calculated. The performances of Na3MgZr（PO4）3：Dy^3＋ make it a potential single-phase white emission phosphor for warm white light emitting diode.To explore suitable single-phase white emission phosphors for warm white light emitting diodes, a series of novel phosphors Na3MgZr（PO4）3：xDy^3＋（0 ≤ x ≤ 0.03） is prepared, and their phase purities as well as photoluminescence properties are discussed in depth via x-ray diffraction structure refinement and photoluminescence spectrum measurement.The electronic structure properties of the Na3MgZr（PO4）3host are calculated. The results reveal that Na3MgZr（PO4）3 possesses a direct band gap with a band gap value of 4.917 eV. The obtained Na3MgZr（PO4）3：Dy^3＋ phosphors are all well crystallized in trigonal structure with space group Rc, which has strong absorption around 365 nm and can generate warm white light emissions peaking at 487, 576, and 673 nm upon ultraviolet excitation, which are attributed to the transitions from -4F9/2 to ^6H15/2,^6H13/2, and ^6H11/2 of Dy^3＋ ions, respectively. The optimal doping content, critical distance, decay time, and Commission International de L＇Eclairage（CIE） chromaticity coordinates are investigated in Dy^3＋ ion-doped Na3MgZr（PO4）3. The thermal quenching analysis shows that Na3MgZr（PO4）3：Dy^3＋ has a good thermal stability, and the thermal activation energy is calculated. The performances of Na3MgZr（PO4）3：Dy^3＋ make it a potential single-phase white emission phosphor for warm white light emitting diode.

关 键 词：optical materials optical properties luminescence 

分 类 号：TN312.8[电子电信—物理电子学] O613.71[理学—无机化学]