Synthesis of diamonds in Fe-C systems using nitrogen and hydrogen co-doped impurities under HPHT  

作　　者：孙士帅 徐智慧 崔雯 贾晓鹏 马红安 

机构地区：[1]College of Science,Tianjin University of Technology [2]College of Physics and Materials Science,Tianjin Normal University [3]State Key Laboratory of Superhard Materials,Jilin University

出　　处：《Chinese Physics B》2017年第9期467-470,共4页中国物理B（英文版）

基　　金：Project supported by the National Natural Science Foundation of China(Grant Nos.11504267,11504269,and 51172089);the Open Project of State Key Laboratory of Superhard Materials,Jilin University,China(Grant No.201504);the Doctoral Fund of Tianjin Normal University,China(Grant No.52XB1518)

摘　　要：In this study, we investigate the effect of nitrogen and hydrogen impurities on colors, morphologies, impurity structures and synthesis conditions of diamond crystals in Fe–C systems with C3N6H6 additives at pressures in the range 5.0–6.5 GPa and temperatures of 1400–1700℃ in detail. Our results reveal that the octahedron diamond nucleation in a Fe–C system is evidently inhibited by co-doped N–H elements, thereby resulting in the increase of minimum pressure and temperature of diamond synthesis by spontaneous nucleation. The octahedron diamond crystals synthesized from a pure Fe–C system are colorless, while they become green in the system with C3N6H6 additive. The surface defects of diamond will deteriorate when the nitrogen and hydrogen atoms simultaneously incorporate in the diamond growth environment in the Fe–C system. We believe that this study will provide some important information and be beneficial for the deep understanding of the crystallization of diamonds from different component systems.In this study, we investigate the effect of nitrogen and hydrogen impurities on colors, morphologies, impurity structures and synthesis conditions of diamond crystals in Fe–C systems with C3N6H6 additives at pressures in the range 5.0–6.5 GPa and temperatures of 1400–1700℃ in detail. Our results reveal that the octahedron diamond nucleation in a Fe–C system is evidently inhibited by co-doped N–H elements, thereby resulting in the increase of minimum pressure and temperature of diamond synthesis by spontaneous nucleation. The octahedron diamond crystals synthesized from a pure Fe–C system are colorless, while they become green in the system with C3N6H6 additive. The surface defects of diamond will deteriorate when the nitrogen and hydrogen atoms simultaneously incorporate in the diamond growth environment in the Fe–C system. We believe that this study will provide some important information and be beneficial for the deep understanding of the crystallization of diamonds from different component systems.

关 键 词：high pressure and high temperature diamond N/H impurity catalyst/solvent 

分 类 号：TQ163[化学工程—高温制品工业]