组合抑制剂CCSL浮选分离PbS、ZnS与单斜Fe_(1-x)S的研究  

Floatation separation of galena,sphalerite,and pyrrhotite by combined depressant CCSL

作　　者：白安平[1] 宋永胜[1] 周鹤[1] 

机构地区：[1]北京有色金属研究总院生物冶金国家工程实验室,北京100088

出　　处：《工程科学学报》2017年第8期1152-1158,共7页Chinese Journal of Engineering

基　　金：国家科技支撑计划资助项目(2015BAB12B00)

摘　　要：进行了组合抑制剂CCSL分离方铅矿、闪锌矿与磁黄铁矿的浮选研究.单矿物浮选实验结果表明,浮选过程添加该组合抑制剂时,磁黄铁矿基本不浮,而方铅矿与闪锌矿的可浮性很好.方铅矿与磁黄铁矿混合矿浮选实验结果表明,添加该组合抑制剂时,方铅矿的浮选回收率可达90%以上,而磁黄铁矿基本不浮,从而很好地实现两种矿物的分离;闪锌矿与磁黄铁矿混合矿浮选实验结果表明,添加该抑制剂时也能实现两种矿物的分离,但分离效果不及方铅矿与磁黄铁矿.X射线光电子能谱、红外光谱、Zeta电位测试表明,CCSL处理后的磁黄铁矿表面的醋酸根吸附不是单纯的物理吸附.紫外吸收光谱扫描结果表明,CCSL中的醋酸根并没有阻碍磁黄铁矿表面双黄药的生成,磁黄铁矿可浮性下降仅仅是由于醋酸根对其造成的亲水性大于双黄药造成的疏水性.CCSL中的醋酸根既与磁黄铁矿中的Fe^(3+)发生亲合,又与水中的H^+形成氢键,最终增强了磁黄铁矿的亲水性;而醋酸根对方铅矿和闪锌矿基本没有影响,这是组合抑制剂CCSL能够分离方铅矿、闪锌矿与磁黄铁矿的原因.The flotation separation of galena,sphalerite,and pyrrhotite was investigated with CCSL as a depressant. Flotation test results show that galena and sphalerite can float but pyrrhotite can barely float with CCSL as a depressant. The flotation tests also show that galena can be separated efficiently from pyrrhotite,and that sphalerite can be separated on the whole from pyrrhotite,but the separation efficiency of the former is much better. The X-ray photoelectron spectroscopy（ XPS）,IR spectrum,and Zeta potential analysis results indicate that the interaction of sodium acetate and pyrrhotite is not only physical absorption. The UV spectrum indicates that the decline in floatability of pyrrhotite is due to the hydrophilicity caused by CH_3COO^- being stronger than that caused by dixanthogen,and the xanthate adsorption on pyrrhotite is not prohibited by CH_3COO^-. The CH_3COO^- reacts not only with pyrrhotite,but also with H＋in water as a H-bond,so the pyrrhotite becomes hydrophilic.

关 键 词：CCSL 磁黄铁矿 方铅矿 闪锌矿 浮选分离 

分 类 号：TD952[矿业工程—选矿]