HFO-1336mzz发泡体系硬泡组合聚醚配方的开发  

Formula Development of HFO-1336mzz Blown Premixed Polyol for Rigid Polyurethane Foam

作　　者：熊丽媛 邢益辉 

机构地区：[1]红宝丽集团股份有限公司,南京211300

出　　处：《聚氨酯工业》2017年第B05期67-69,共3页Polyurethane Industry

基　　金：环境保护部“聚氨酯泡沫行业消耗臭氧层物质替代技术研发和推广”项目（C/Ⅲ/S/13/478）.

摘　　要：研究了聚醚多元醇、水分、泡沫稳定剂对聚氨酯硬泡性能的影响，优化并确定了HFO-1336mzz发泡体系组合聚醚配方。结果表明，当配方中多元醇（A／B／C／D质量比为45／35／15／5）100份、泡沫稳定剂MF131为1．5—3．0份、水2．2—2．6份、HFO-1336mzz为25～35份、复合催化剂2．0-2．8份、异氰酸酯指数1．05-1．10时，制得的聚氨酯硬泡的导热系数可低至17．48mW／（m·K）。The effects on foam properties by polyether polyols, moisture content, iscoyanate and foam stabiliz- ers were researched in this paper, and furthermore the formula of HFO-1336mzz blown premixed polyol was opti- mized and confirmed. The result showed that the thermal conductivity of HFO-1336mzz-blown rigid polyurethane foam could be as low as 17.48 mW/（m.K）, with polyether polyols 100 parts by weight, and the mass fraction of polyol A/B/C/D was 45/35/15/5, the foam stabilizer MF131 was 1.5 - 3.0 parts, water was 2. 2 - 2.6 parts, HFO-1336mzz was 25-35 parts, mixed catalyst was 2. 0-2. 8 parts, the isocyanate index was 1.05~ 1.10.

关 键 词：HFO-1336mzz 发泡剂 组合聚醚 聚氨酯硬泡 

分 类 号：TQ328.3[化学工程—合成树脂塑料工业]