原位结合相对刚玉-尖晶石浇注料结构与性能的影响  

Effect of In-situ Formed Phases on Microstructure and Properties of Corundum-Spinel Castable

作　　者：文泽宇 李享成[1] 余珊珊 陈平安[1] 朱伯铨[1] 

机构地区：[1]武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉430081 [2]武汉三工光电设备制造有限公司,武汉430233

出　　处：《硅酸盐学报》2017年第9期1347-1353,共7页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金(51374162)资助

摘　　要：以板状刚玉、电熔镁铝尖晶石、活性α-Al_2O_3微粉等为主要原料、铝酸钙水泥为结合剂,制备刚玉尖晶石浇注料。利用X射线衍射和扫描电子显微镜等研究了不同热处理温度下材料显微结构演化及对其性能的影响。结果表明:1 100℃烧成后,试样中尖晶石与氧化铝的固溶反应及八面体形貌原位尖晶石的生成使得试样有较高的中温力学性能。板片状形貌的六铝酸钙(CA6)的生成提高了1 600℃烧后试样的综合性能,试样的高温抗折强度提高近219%,达到24.18 MPa;3次热震后试样的常温抗压强度损失为15.5 MPa,强度保持率提升近14%,达到84.50%。板片状CA6的生成显著提高了浇注料试样的热震性和抗渣性。The corundum-spinel castables were prepared with tabular alumina, fused magnesium aluminate spinel, reactive a-Al2O3 powder as main raw materials. The calcium aluminate cement was used as a binder. The effect of calcination temperature on the microstructural evolution and properties of refractories was investigated by X-ray diffraction and scanning electron microscopy. The results show that the specimen sintered at 1 100 ℃ has higher medium-temperature mechanical properties due to the formation of in situ spinel with an eight-surface shape and the solid solution reaction of spinel and Al2O3 . The formation of calcium hexaluminate （CA6） promotes the comprehensive performance of designed refractories at 1 600 ℃ due to the platelet shape of these crystals. The hot modulus of rupture can be increased by 219% （i.e., 24.18 MPa）. It is also found that after three thermal shock cycles, the decreased cold crushing strength is only 15.47 MPa, and the keeping rate of strength of the specimen is increased by 14% （i.e., 84.50%）. The formation of CA6 improves the thermal shock resistance and slag resistance of the refractories.

关 键 词：浇注料 结构演化 尖晶石 六铝酸钙 

分 类 号：TQ175.1[化学工程—硅酸盐工业]