离子色谱同时测定脱硫脱硝副产物中SO_3^(2-)、SO_4^(2-)、NO_2^-、NO_3^-方法研究  

DETERMINATION OF SULFITE,SULFATE RADICAL,NITRITE AND NITRATE IN THE DESULFURIZATION AND DENITRIFICATION BY-PRODUCT BY ION CHROMATOGRAPHY

作　　者：王志鹏[1] 李鹏飞[2,3] 龚迎莉[1] 禚玉群[1] 佟会玲[1] 俞非漉[2,3] 

机构地区：[1]清华大学热科学与动力工程教育部重点实验室,北京100084 [2]中冶建筑研究总院有限公司,北京100088 [3]中冶节能环保有限责任公司,北京100088

出　　处：《环境工程》2017年第8期163-167,共5页Environmental Engineering

基　　金：国家自然科学基金"脱硫石膏中有害痕量元素再释放机理研究"(51376109)

摘　　要：使用离子色谱测脱硫脱硝副产物中的亚硫酸根、硫酸根、亚硝酸根、硝酸根4种离子,研究通过加甲醛抑制亚硫酸根的氧化,研究甲醛对4种离子,以及4种离子之间在测定时是否会相互影响。结果发现:硫酸根、亚硝酸根、硝酸根3种离子比较稳定,而SO_3^(2-)易被氧化。发现采用甲醛作为抗氧化剂可以较好地抑制SO_3^(2-)的氧化;用1 mmol/L的KOH作为淋洗液时,甲醛的质量分数可选为0.05%,若甲醛浓度过高,除影响色谱柱寿命外,SO_3^(2-)的出峰面积也会变小。甲醛的加入不影响亚硝酸根和硝酸根的出峰。亚硫酸根、硫酸根、亚硝酸根、硝酸根同时测定过程中相互干扰不大,4种离子的线性关系较好。采用甲醛做抗氧化剂时,不应采用Na_2CO_3等弱碱溶液作为淋洗液。总之,通过加入适量的甲醛,离子色谱法可以准确同时测定脱硫脱硝产物的亚硫酸根、硫酸根、亚硝酸根、硝酸根4种离子。Ion chromatography was used for measurement of sulfite,sulfate,nitrate and nitrite ions that leaching from the by products of simultaneous desulfurization and denitrification by calcium based sorbent. The study focused on the stability of single ions and interactions of the four kinds of ions. It is found that sulfate,nitrate and nitrite ions were stable,however,sulfite ion could be easily oxidized. Formaldehyde was used as stabilizing agent to prevent sulfite ion effectively from being oxidized effectively. However,the mass percentage of formaldehyde should be less than 0. 05% when KOH solution is used as the pour lotion,since excess formaldehyde would decrease SO3^2-peak area and also had negative effect on the chromatographic column. Formaldehyde had no effect on the measurement of nitrate and nitrite ions. During the determination process,it was found that these four ions had little interference,and all ions showed good linearity. If alkalescent solution（ like Na2CO3） was used as pour lotion,formaldehyde should not be used as oxidation inhibitor. In conclusion,sulfite,sulfate,nitrate and nitrite ions could be accurately determined by ion chromatography with addition of proper dosage of formaldehyde in the solution.

关 键 词：离子色谱 亚硝酸根 亚硫酸根 硝酸根 甲醛 

分 类 号：X701[环境科学与工程—环境工程] X831