烯烃聚合用聚合物负载催化剂研究进展  

Research progress in polymer supported catalysts for olefin polymerization

作　　者：姜艳峰 王登飞[1] 韦德帅[1] 李瑞[1] 国海峰[1] 葛腾杰[1] 

机构地区：[1]中国石油天然气股份有限公司石油化工研究院大庆化工研究中心,黑龙江大庆163714

出　　处：《工业催化》2017年第8期14-19,共6页Industrial Catalysis

摘　　要：为满足目前聚烯烃聚合工艺的要求,防止催化剂双分子失活,使聚合过程平稳,催化剂需要进行负载。由于现阶段使用的无机物(Si O2、Mg Cl2等)载体存在很多缺陷,只能满足一般通用材料的要求,使其应用受到限制。有机高分子载体相对结构明确,表面官能团可调,无机灰分低。综述烯烃聚合用聚合物负载催化剂的研究进展,主要分为聚苯乙烯载体、聚硅氧烷载体和其他聚合物载体。In order to meet the requirements of the current polyolefin polymerization process,prevent the catalyst bimolecular inactivation and make the polymerization process stable, the catalysts need to be load- ed. Due to the shortcomings of the inorganic （ Si02, MgCl2, etc. ） carriers used at present, their applica- tion is limited in high demanding fields. Organic polymer carrier has the advantages of clearly relative structure, adjustable surface functional group, and low inorganic ash. The research progress in the polymer carriers for supported polyolefin catalysts was reviewed. It was mainly divided into three types：polystyrene carrier, polysiloxane carrier and other polymer carrier.

关 键 词：有机化学工程 聚烯烃催化剂 聚合物 

分 类 号：TQ325.1[化学工程—合成树脂塑料工业] TQ426.94