几类含氮离子化合物的微波合成及催化Perkin反应  

Microwave synthesis and catalytic Perkin reaction of nitrogen ionic compounds

作　　者：王金娟[1] 裴学海 杨志翔[1] 王文琛[1] 陈治明[1] 

机构地区：[1]贵州师范大学化学与材料科学学院贵州省功能材料化学重点实验室,贵州贵阳550001

出　　处：《贵州师范大学学报（自然科学版）》2017年第4期105-108,共4页Journal of Guizhou Normal University：Natural Sciences

基　　金：国家自然科学基金(No.21362006);贵州省自然科学基金(黔科合J字[2009]2021)

摘　　要：以N-乙基哌啶、N-甲基吗啉为原料,采用微波合成方法合成了6种离子化合物。产物结构经1H NMR确认。探讨了价廉易得,环境友好和无毒性的离子化合物催化的芳香醛与乙酸酐的Perkin反应。该反应具有催化剂经济易得及其用量少、反应条件温和、环境友好和易操作等优点。Six ionic compounds were synthesized using N-ethyl piperidine,N-methyl morpholine as materials under microwave condition. The structures were characterized by 1H NMR. An inexpensive and environmentally friendly ionic compounds catalyzed Perkin reaction of aromatic aldehydes with acetic anhydride has been developed. The procedure was characterized by lower amount of inexpensive catalyst,mild reaction condition,environmentally benign and simplicity.

关 键 词：离子化合物 微波合成 PERKIN反应 

分 类 号：O621.3[理学—有机化学]