A N-tripodal Ligand Cu-Based Coordination Polymer with Good Catalytic Activity for the Reduction of 4-Nitrophenol  

作　　者：金矿 胡劲松 吕超南 刘俊 李盛雨 程婷婷 周春辉 何志伟 张明道 

机构地区：[1]School of Chemical Engineering, Anhui University of Science and Technology [2]Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control (AEMPC), School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology

出　　处：《Chinese Journal of Structural Chemistry》2017年第8期1361-1367,共7页结构化学（英文）

基　　金：Supported by the National Natural Science foundation of China(21301005,21671004,51404006);Natural Science Foundation of Anhui Province(1408085QB31);the open fund of Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(KFK201508)

摘　　要：A complex {[Cu（tib）2（H2O）2]·（NO3）2}n（1） has been synthesized under N,N-dimethylacetamide（DMA） and water conditions. The structure of complex 1 was characterized by single-crystal X-ray crystallography. It crystallizes in monoclinic, space group P21/n with a = 10.6273（7）, b = 11.4184（7）, c = 13.4215（8） A, β = 108.290（2）°, V = 1546.38（17）A3, Z = 2, F（000） = 798, Dc = 1.667 g/cm3 and m = 0.786 mm-1） Complex 1 exhibits a 3D network due to the existence of O–H…O interaction between coordinated water and nitrate anions. Furthermore, complex 1 has a good catalytic activity for the reduction of 4-nitrophenol in Na BH4 solution.A complex {[Cu（tib）2（H2O）2]·（NO3）2}n（1） has been synthesized under N,N-dimethylacetamide（DMA） and water conditions. The structure of complex 1 was characterized by single-crystal X-ray crystallography. It crystallizes in monoclinic, space group P21/n with a = 10.6273（7）, b = 11.4184（7）, c = 13.4215（8） A, β = 108.290（2）°, V = 1546.38（17）A3, Z = 2, F（000） = 798, Dc = 1.667 g/cm3 and m = 0.786 mm-1） Complex 1 exhibits a 3D network due to the existence of O–H…O interaction between coordinated water and nitrate anions. Furthermore, complex 1 has a good catalytic activity for the reduction of 4-nitrophenol in Na BH4 solution.

关 键 词：coordination polymer CATALYSIS reduction of nitrophenol 

分 类 号：O634[理学—高分子化学]