Solvent-Free Synthesis of ITQ-12, ITQ-13, and ITQ-17 Zeolites  

作　　者：Qinming Wu Xiaolong Liu Longfeng Zhu Xiangju Meng Feng Deng Fengtao Fan Zhaochi Feng Can Li Stefan Maurer Mathias Feyen Ulrich Muller Feng-Shou Xiao 

机构地区：[1]Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310007, China [2]State Key Laboratory of Magnetic Resonance andAtomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China [3]College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China [4]State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China [5]BASF Catalysts (Shanghai) Co., Ltd., 239 Luqiao Road, Jinqiao Export Process Zone Pudong New District, Shanghai 201206, China [6]Process Research and Chemical Engineering, BASF SE, 67056, Ludwigshafen, Germany

出　　处：《Chinese Journal of Chemistry》2017年第5期572-576,共5页中国化学（英文版）

摘　　要：Development of the sustainable routes for synthesis of ITQ-family zeolites is very important because of their unique structures and excellent catalytic and adsorptive properties.The burden of costly raw materials and low efficiency of synthesis put a strong challenge for their widespread commercial application.Here,we show an alternative and simple route for synthesis of ITQ-12,ITQ-13,and ITQ-17 zeolites using commercially available organic templates by a facile grinding process of anhydrous starting raw solids,followed by heating at 140-180 ℃.Compared with the conventional hydrothermal synthesis,this approach has obvious advantages such as employment of low-cost organic templates with very high effectiveness,high yield of zeolite products,short crystallization time,and relatively simple procedures.This methodology might open a pathway to synthesize ITQ zeolites with more sustainable manner.Development of the sustainable routes for synthesis of ITQ-family zeolites is very important because of their unique structures and excellent catalytic and adsorptive properties.The burden of costly raw materials and low efficiency of synthesis put a strong challenge for their widespread commercial application.Here,we show an alternative and simple route for synthesis of ITQ-12,ITQ-13,and ITQ-17 zeolites using commercially available organic templates by a facile grinding process of anhydrous starting raw solids,followed by heating at 140-180 ℃.Compared with the conventional hydrothermal synthesis,this approach has obvious advantages such as employment of low-cost organic templates with very high effectiveness,high yield of zeolite products,short crystallization time,and relatively simple procedures.This methodology might open a pathway to synthesize ITQ zeolites with more sustainable manner.

关 键 词：ZEOLITE sustainable route solvent-free synthesis low-cost organic template ITQ-family 

分 类 号：O[理学]