新型无烟阻燃材料聚氧化磷腈的合成及性能研究  

Synthesis and Properties of Polyphosphazene Oxide:a Novel Smoke-free Flame Retardant Material

作　　者：王晓丹[1] 马慧[2] 刘玉存[2] 周艳明 郭嘉昒[1,2] Wang Xiaodan Ma Hui Liu Yucun Zhou Yanming Guo Jiahu(Sichuan Staff University of Science and Technology, Chengdu 610101, China School of Chemical and Environmental Engineering, North University of China, Taiyuan 030051, China Shanxi Research Institute of Applied Chemistry, Taiyuan 003207, China)

机构地区：[1]四川科技职工大学,成都610101 [2]中北大学化工与环境学院,太原030051 [3]山西应用化学研究所,太原003207

出　　处：《绝缘材料》2017年第9期25-29,共5页Insulating Materials

基　　金：国家自然科学基金委员会和中国工程物理研究院联合基金资助项目(U1330131);四川省安全生产科技项目(aj20170518104846)

摘　　要：设计了一种具有新型结构特征的磷腈聚合物——聚氧化磷腈。以三氯氧磷和六亚甲基四胺为原料,以1-氯萘为溶剂,在170℃下反应32 h,成功合成聚氧化磷腈,通过FTIR和^(31)PNMR对聚合物的结构进行表征。然后以聚氧化磷腈作为反应型阻燃剂制得阻燃环氧树脂E51,并测试其性能。结果表明:采用聚氧化磷腈改性的阻燃环氧树脂E-51氧指数为35.4%,垂直燃烧等级为UL94 V-0,阻燃效果良好。A novel structured phosphazene polymer, which called polyphosphazene oxide, was designed. The polyphosphazene oxide was successfully synthesized at 170 ℃ for 32 h using phosphorus oxychloride and hexamine as raw materials, 1-chloronaphthalene as solvent, and its structure was characterized via FTIR and ^31P-NMR. Then a flame retardancy epoxy resin （E51） was prepared using polyphosphazene oxide as reactive flame retardant, and its properties were tested. The results show that the oxygen index of the polyphosphazene oxide modified E51 is 35.4%, and the vertical burning level is UL94 V-0, which indictae that the E51 has good flame retardant efficiency.

关 键 词：阻燃 聚氧化磷腈 环氧树脂 氧指数 

分 类 号：TM215.13[一般工业技术—材料科学与工程]