Cu(Ⅰ)-BCA催化水合肼绿色选择性还原芳香族硝基化合物  

Selective Green Reduction of Nitroarenes with Hydrazine Hydrate Catalyzed by Cu(Ⅰ)-BCA

作　　者：沈娟[1] 蔡俊 伍斌[1] 冯志明[1] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081

出　　处：《广东化工》2017年第17期6-6,3,共2页Guangdong Chemical Industry

基　　金：湖南师范大学科研项目(化160703)

摘　　要：获得了一种温和的将芳香族硝基化合物选择性还原为相应的芳胺的方法,产率高,反应温度仅80℃。这一方法特别适用于分子中存在如Cl,Br和COCH_3等还原性基团的芳香族硝基化合物的还原,反应清洁高效,Cu(Ⅰ)-BCA催化剂可重复使用。A mild and selective reduction of nitroarenes to the corresponding amino derivatives has been achieved by a combination of metal and hydrazine hydrate in good to excellent yields at 80℃. The reductions are successfully carried out in presence of other reducible functional groups in the molecule, such as Cl, COCH3. The reactions are very clean and high yielding, the metal catalyst are reusable.

关 键 词：芳香族硝基化合物 铜 水合肼 还原 

分 类 号：TQ031.6[化学工程]