Copper(Ⅱ) Acetylacetonate: An Efficient Catalyst for Huisgen- Click Reaction for Synthesis of 1,2,3-Triazoles in Water  

Copper(Ⅱ) Acetylacetonate: An Efficient Catalyst for Huisgen- Click Reaction for Synthesis of 1,2,3-Triazoles in Water

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作  者:Yuqin Jiang Xingfeng Li Xiyong Li Yamin Sun Yaru Zhao Shuhong Jia Niu Guo Guiqing Xu Weiwei Zhang 

机构地区:[1]Henan Engineering Laboratory of Chemical Pharmaceuticals' & Biomedical Materials, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China [2]Weihai Ocean Vocational College, Weihai, Shandong 264300, China

出  处:《Chinese Journal of Chemistry》2017年第8期1239-1245,共7页中国化学(英文版)

摘  要:An efficient and green copper(Ⅱ) acetylacetonate-catalyzed protocol for the Huisgen-click reaction in water at 100℃ has been established. The protocol was not only suitable for the reaction between organic azides and alkynes, but also suitable for one-pot three-component reaction among alkyl halides, NaN3 and alkynes.An efficient and green copper(Ⅱ) acetylacetonate-catalyzed protocol for the Huisgen-click reaction in water at 100℃ has been established. The protocol was not only suitable for the reaction between organic azides and alkynes, but also suitable for one-pot three-component reaction among alkyl halides, NaN3 and alkynes.

关 键 词:copper(Ⅱ) acetylacetonate Huisgen-click reaction WATER ALKYNES ONE-POT 

分 类 号:O614.121[理学—无机化学] TQ463.25[理学—化学]

 

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