DOC/SCR组合方式及关键参数对NO_x转化效率的影响  

Influence of combinations and key parameters on NO_x conversion efficiency in DOC/SCR system

作　　者：孟忠伟 晋兆祥 陈超 李健 刘苗 陈秋宇 闫妍 柏威廉 方嘉 MENG Zhongwei JIN Zhaoxiang CHEN Chao LI Jian LIU Miao CHEN Qiuyu YAN Yan BAI Weilian FANG Jia(Sichuan Collaborative Innovation Center for Automotive Key Components, School of Automotive and Transportation Engineering, Xihua University, Chengdu 610039, China Key Laboratory of Fluid and Power Machinery （Xihua University）, Ministry of Education, Chengdu 610039, China Zhejiang Tong Yuan Material Tech. ,Ltd. , Wenling 317500, China)

机构地区：[1]西华大学汽车与交通学院四川汽车关键零部件协同创新中心,成都610039 [2]流体及动力机械教育部重点实验室(西华大学),成都610039 [3]浙江通源材料有限公司,温岭317500

出　　处：《环境工程学报》2017年第10期5483-5489,共7页Chinese Journal of Environmental Engineering

基　　金：国家自然科学基金资助项目(51106130);教育部"春晖计划"合作科研项目(Z2014058);发动机燃料电控系统及尾气后处理系统产业集群项目(成财教[2013]265);流体及动力机械教育部重点实验室开放课题(SZJJ2016-005);西华大学重点科研基金项目(Z1120319);西华大学研究生创新基金项目(YCJJ2015040;YCJJ2016087)

摘　　要：在柴油机中等转速下,通过改变柴油机氧化催化器(DOC)和选择性催化还原催化器(SCR)的组合方式,以及改变喷嘴位置、两级SCR载体间距和催化剂成分,获得各种条件下的NO_x转化效率,为优化组合方式和关键参数提供重要数据支撑。结果表明:增加尿素喷嘴与SCR入口的相对距离,NO_x转化效率升高,喷嘴距离为45 cm较为合适;载体间距的增大,NO_x转化效率先略有升高,后急剧下降,间距为2 cm较为合适;载体体积增大,NO_x转化效率明显升高,在满足目标NO_x转化效率的前提下,载体体积不宜过大;DOC与SCR的组合方式对NO_x转化效率具有明显差异,前置DOC能够有效的提高NO_x转化效率;在催化条件下,NO_x转化效率由高到低排序为:铜基>钒基>铁基;对于复合催化剂而言,铜铁复合基>铁铜复合基。Based on the condition of medium speed of diesel engine,the NO_x conversion efficiency were obtained by changing the combination modes between DOC and SCR components,varying the position of the nozzle,the intervals of two SCR substrates and the catalyst composition,in order to provide important data support for optimizing the combination mode and the key parameters.The results showed that increasing the relative distance between the urea＇s nozzle and the SCR substrate,NO_x conversion efficiency increased,and the distance of 45 cm was the optimized distance.Increasing the interval of the SCR substrates,NO_x conversion efficiency increased firstly and then decreased sharply,and the interval of 2 cm was the optimized distance.Increasing the substrate volume,and NO_x conversion efficiency increased significantly,while the substrate volume was not suitable to be larger after meeting the target of NO_x conversion efficiency.The NO_x conversion efficiency could be significantly affected by the changing the combination mode between DOC and SCR substrate,and the pre-DOC can effective-ly improve the NO_x conversion efficiency.Under catalytic conditions,the descending order of NO_x conversion efficiency was： Copper-based Vanadium-based Iron-based; under the composite catalysts condition,the descending order was： Copper-Iron complex based Iron-Copper complex based.

关 键 词：柴油机 尾气后处理系统 关键参数 组合方式 NOx转化效率 

分 类 号：TK424.5[动力工程及工程热物理—动力机械及工程]