α,β-不饱和羰基化合物的合成研究进展  

Research Progress on the Synthesis of α,β-unsaturated Carbonyl Compounds

作　　者：程玉桥 杨光[1] 张贤松 梁书芹 薛莉娜 杜婷婷 

机构地区：[1]天津工业大学环境与化学工程学院,天津300387 [2]中海油研究总院技术研发中心,北京100028

出　　处：《合成化学》2017年第10期871-880,共10页Chinese Journal of Synthetic Chemistry

摘　　要：α,β-不饱和羰基化合物是制备多种新型驱油材料的重要中间体,可以通过偶联、加成等反应实现功能材料分子官能团的多样化、结构的多元化以及材料性能的高效化。对α,β-不饱和羰基化合物的合成方法(羟醛缩合反应、丙二酸加成-脱羧反应、斯托伯反应、Knoevengel反应、Reformasky反应、曼尼希反应等)进行了综述。参考文献30篇。α,β-Unsaturated carbonyl compounds are the most important intermediates to prepare novel oil displacing materials. They can be used in addition and coupled reactions to link one molecule to an- other, in order to diversify the function group and structure, and intensify the material performance. The synthetic methods of α,β-unsaturated carbonyl compounds were reviewed with thirty references, including aldol condensation, malonic acid addition-decarboxylation, Stober reaction, Knoevengel re- action, Reformasky reaction, etc.

关 键 词：Α Β-不饱和羰基化合物 合成方法 新材料 综述 

分 类 号：O621.25[理学—有机化学] O621.3[理学—化学]