丝叶唐松草中—新三萜皂甙(英文)  被引量:1

A New Triterpene Glycoside of Thalictrum Foeniculaceum

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作  者:易以军[1] 吴知行[1] 

机构地区:[1]中国药科大学天然药物化学教研室

出  处:《中国药科大学学报》1991年第5期270-274,共5页Journal of China Pharmaceutical University

摘  要:从丝叶唐松草根中分得一新的三萜皂甙,命名为thalifoenoside A,根据光谱和化学方法确定其结构为3β,22(S),27-三羟基-24-烯-环菠萝蜜烷,3-O-β-D-鸡纳糖基-(1→2)-α-L-鼠李糖基-(1→6)-β-D-(4-乙酰基)-葡萄糖甙,其甙元亦为一新的化合物。此外还分到3个已知物thalifendlerine,N-methylcorydaldine,β-谷甾醇。A new triterpene glycoside named thalifoenoside A in which aglycone was new 3β, 22(S), 27-trihydroxy-24-en-cycloartane, was isolated from the root of thalictrum foeniculaceum and its structure was determined on the basis of spectroscopic evidences and analysis of its hydrolysates. It was identified as 22(S), 27-dihydroxy-24-en-cycloartane-3β-y1 β-D-quinovopyranosyl-(1→2)-α-L-rhamnopyranosyl-(1→6)-β-D-4-acetyl-glucoside. Besides, the known compounds thalifendlerine, N-methylcorydaldine and β-sitosterol were isolated.

关 键 词:丝叶唐松草 三萜皂甙 生物碱 

分 类 号:R284.1[医药卫生—中药学]

 

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