氯桥钌配位聚合物[(C5Me5)RuCl2]n的合成及表征  

Synthesis and Characterization of Chloride-bridged Ruthenium [(C_5Me_5)RuCl_2]_n Polymer

作　　者：晏彩先[1] 李杰[1] 姜婧[1] 陈家林[1] 刘伟平[1] 常桥稳[1] 

机构地区：[1]昆明贵金属研究所,贵研铂业股份有限公司,稀贵金属综合利用新技术国家重点实验室,昆明650106

出　　处：《贵金属》2017年第B10期120-123,共4页Precious Metals

基　　金：云南省省院省校科技合作项目(2015IB019);昆明市科技计划项目(2016-1-G-03331)

摘　　要：对一步反应合成二氯(五甲基环戊二烯基)合钌(Ⅲ)聚合物[(C5Me5)RuCl_2]_n的方法进行改进,将原料中水合三氯化钌与配体的摩尔比调整为1:1.66,采用氩气保护的无水无氧制备装置,产率达到80%。元素分析、红外光谱(IR)、核磁共振(~1H-NMR)的表征结果证实了目标产物结构。[（C5Me5）RuCl2]n has been synthesized through one-step reaction. Preparation method has been improved and optimized, thus the productivity was up to 80%, which was higher than reproted values of literature. Structure of the complexes have been represented by the structural analytical methods like elemental analysis, IR,1H-NMR, then their chemical construction were confirmed finally.

关 键 词：有机金属配合物 二氯(五甲基环戊二烯基)合钌(Ⅲ)聚合物 合成 结构 

分 类 号：O627.8[理学—有机化学]