马来海松酸衍生物手性识别能力的NMR研究  

NMR Studies of Chiral Recognition Abilities of Maleopimaric Acid Derivatives

作　　者：吴强 肖资龙 王龙超 文长春 刘佩 Wu Qiang Xiao Zilong Wang Longchao Wen ChangChun Liu Pei(School of Chemistry ＆ Pharmaceutical Sciences of Guangxi Normal University, Guilin 541004, China)

机构地区：[1]广西师范大学化学与药学学院,广西桂林541004

出　　处：《广东化工》2017年第20期4-5,共2页Guangdong Chemical Industry

基　　金：广西科学研究与技术开发计划项目(桂科能14123006-13)

摘　　要：以松香为原料合成马来海松酸衍生物,用作助剂制备NMR手性膦衍生化试剂,并通过测定31P NMR检验马来海松酸衍生物用于NMR手性识别的能力,结果显示,所合成的马来海松酸衍生物3可用于制备方便有效的手性衍生化试剂。Maleopimaric acid derivatives was synthesized using rosin acid as the starting materials, and used as chiral auxiliary for chiral phosphorus derivatizing agents（CPDAs）, the chiral recognition abilities of compound 3 was studied by 31p NMR spectroscopy, the result demonstrated that compound 3 can be used as a convenient and effectual chiral derivatizing reagent.

关 键 词：马来海松酸单乙酯 NMR 手性识别 

分 类 号：TQ630.4[化学工程—精细化工]