一次消解土壤样品测定汞、砷和硒  

Determination of Mercury,Arsenic and Selenium in Soils by One-time Digestion

作　　者：钱薇[1,2] 唐昊冶 王如海[1,2] 龚华[1] 蒋倩 俞元春[2] 

机构地区：[1]中国科学院南京土壤研究所土壤与农业可持续发展重点实验室,南京210008 [2]南京林业大学南方现代林业协同创新中心南京林业大学生物与环境学院,南京210037

出　　处：《分析化学》2017年第8期1215-1221,共7页Chinese Journal of Analytical Chemistry

基　　金：国家自然科学基金项目(Nos.41230855;31670615;31270664)资助~~

摘　　要：建立了测定土壤中3种挥发性元素(汞、砷、硒)的一次消解方法,确定以程序控温石墨自动消解仪+王水-氢氟酸-硼酸络合敞开体系为最佳消解体系,采用氢化物发生-原子荧光光谱法(HG-AFS)分别测定同一消解液中汞、砷、硒的含量。采用国家标物中心有证标准物质土壤环境样品GSS-1~GSS-8进行了方法验证,结果均符合标准偏差的允许范围。此消解方法相比于现行标准方法,避免了针对各元素的分次处理,简化了消解步骤,节省了前处理时间,减少了试剂消耗,提高了实验效率,适用性广、灵敏度高、检出限低,尤其适合批量样品的微量/痕量元素分析,可作为一种大规模土壤样品中重金属污染监测和治理的快捷方法。A method for the determination of three volatile elements （ mercury, arsenic and selenium） in soils by one-time digestion was established. The digestion of samples was carried out in an automatic program temperature controlled graphite digestion instrument by aqua regia ＋ hydrofluoric acid ＋ boric acid. Hydride generation atomic fluorescence spectrometry （ HG-AFS ） was used to determine the contents of mercury, arsenic and selenium in the same digestion solution. The accuracy of the method was verified by the results of the soil environment samples of certified reference materials GSS- 1 -GSS-8 from the Center of the National Standard. The contents of soil mercury, arsenic and selenium obtained by this method were consistent with the standard values of these elements provided by the Center of the National Standard. In comparison with the current standard methods, the one-time digestion method was simplified, the pre-processing time was saved, and the reagent consumption was reduced. The method had wide range of application, high sensitivity, low detection limit, which was especially suitable for trace analysis of bulk samples, and also it could be used as a rapid digestion method for the measurement and governance of heavy metals in polluted soils.

关 键 词：土壤 汞 砷 硒 王水 氢氟酸 硼酸 一次消解 原子荧光光谱 

分 类 号：O657.31[理学—分析化学] X833[理学—化学]