N^3,N^6-二(9,9-二甲基芴-2-基)-N^3,N^6-二(9-苯基咔唑-3-基)-9-苯基咔唑-3,6-二胺的合成  

Synthesis and Characterization of N^3,N^6-Di(9,9-dimethyl-9H-fluoren-2-yl)-N^3,N^6-Bis(9-phenyl-9H-carbaz-ol-3-yl)-9-phenyl-9H-carbazole-3,6-diamine

作　　者：司江坤 孙雨安[2] 杨振强[3] 杨瑞娜[3] 

机构地区：[1]新疆兵团现代绿色氯碱化工工程研究中心(有限公司),新疆石河子832000 [2]郑州轻工业学院应用化学系,河南郑州450002 [3]河南省科学院化学研究所有限公司,河南郑州450002

出　　处：《化工技术与开发》2017年第11期12-14,18,共4页Technology & Development of Chemical Industry

摘　　要：以3,6-二溴-9-苯基咔唑和N-(9,9-二甲基芴-2-基)-9-苯基咔唑-3-胺为原料,经Buchwald-Hartwig偶联反应,合成了一种含芴咔唑类空穴传输材料N^3,N^6-二(9,9-二甲基芴-2-基)-N^3,N^6-二(9-苯基咔唑-3-基)-9-苯基咔唑-3,6-二胺。利用~1H NMR、^(13)C NMR和IR等分析方法对产物结构进行了表征,并通过DSC-TG、UV-Vis和荧光光谱研究了物质的热稳定性和光学性能。A hole-transporting material N3,N6-di（9,9-dimethyl-9H-fluoren-2-yl）-N3, N6-bis（9-phenyl-9H-carbazol-3-yl）-9-phenyl-9H-carbazole-3,6-diamine, was synthesized by NBS electrophonic substitution reaction and Buchwald-Hartwig coupling reaction from 3,6-dibromo-9-phenyl-9H-carbazole and N-（9,9-dimethyl-9H-？uoren-2-yl）-9-phenyl-9H-carbazol-3-amine. The structure of as-synthesized compound was characterized by 1H NMR, 13C NMR and IR. Thermal properties and optical properties were determined by TG, UV-Vis and ？uorescence spectrum.

关 键 词：空穴传送材料 合成 表征 光学性能 热稳定性 

分 类 号：O626.13[理学—有机化学] O625.63[理学—化学]