地球化学工程技术修复江西某Pb超标耕地的应用  

The Application of Geochemical Engineering Technology to the Remediation of a Pb Polluted Abandoned Farmland in Jiangxi Province

作　　者：谭科艳[1] 王喆 蔡敬怡[1,2] 陈燕芳 王卓 刘久臣 汤奇峰[1] 袁欣[1] 杨宏[4] 

机构地区：[1]中国地质科学院国家地质实验测试中心,北京100037 [2]中国地质大学(北京),北京100083 [3]浙江省地质矿产研究所,浙江杭州310007 [4]北京工业大学,北京100124

出　　处：《地球学报》2017年第6期953-960,共8页Acta Geoscientica Sinica

基　　金：国家公益性行业科研专项(编号:201211078);中国地质科学院基本科研业务费项目(编号:YYWF201722;YYWF201617)联合资助~~

摘　　要：为了判别地球化学材料在土壤改良与重金属修复中的作用,本研究以江西龙南某地被稀土采矿废水污染而废弃的农耕地为对象,用黏土矿物等材料组成的三种修复方案对249 km2的废弃地进行修复。一周期后,比较修复前后土壤中重金属生物易迁移态的变化来评价该技术的有效性。结果表明,该地Pb超标程度最重,达101.50 mg·kg-1。Cd、Hg、As次之,分别为0.13 mg·kg-1、0.13 mg·kg-1、2.98 mg·kg-1,均超赣州市土壤背景值含量,超龙南地区土壤Pb的均值,修复目标为Pb。该地土壤中Pb的易迁移态含量与总量不显著相关。经地球化学工程技术修复后,Pb易迁移态降低了3.25%,修复效果明显。一周期后,Pb的易迁移态平均降幅为1.40%,修复效果稳定。修复效果最佳的方案C能使Pb降低幅度达到3.38 mg·kg-1,在经济上体现为最廉价,体现了地球化学工程技术的优势。For the purpose of determination of the effect of geochemical materials in soil improvement and heavy metal remediation, three remediation methods were used on a 249 m2 abandoned land in Longnan area of Jiangxi province, where farmland was abandoned due to wastewater pollution from rare earth mining. The technical effectiveness of these three methods was evaluated after one cycle of comparing changes of the easy-migrate-speciation of heavy metals in the soil before and after remediation. The results showed that the element of highest degree of excess was Pb with the amount of 101.50 mg·kg-1, followed by Cd（0.13 mg·kg-1）, Hg（0.13 mg·kg-1） and As（2.98 mg·kg-1） which all exceeded the background value of soil in Ganzhou, Longnan. Pb, which exceeded the average soil Pb content in Longnan, was selected as the remediation target. In the soil of this area, the content of available Pb was not significantly correlated with the total amount. Using geochemical engineering technology, the authors detected that the treatment effect was obvious, as shown by the fact that the easy-migrate-speciation of Pb decreased by 3.25%. After one cycle, the repair effect was stable with reduction of Pb easy-migrate-speciation by 1.40% on average. Method C is considered to be the best solution with the reduction of Pb by 3.38 mg·kg-1, and its cost is the cheapest.

关 键 词：修复 重金属 地球化学工程技术 易迁移态 效果 

分 类 号：X53[环境科学与工程—环境工程] X751