玻璃衬底温度对溅射制备SnO_2-Al_2O_3双金属元素薄膜电学及光学特性的影响（英文）  

Influence of Substrate Temperature on Electrical and Optical Properties of Sputtered Binary SnO_2-Al_2O_3 Thin Films on Slide Glasses

作　　者：李院院[1] 罗文峰[2] 李姝丽[1] 成桢[1] 赵小侠[1] 贺俊芳[1] 张鹏飞 徐可为[1] 

机构地区：[1]西安文理学院陕西省表面工程与再制造重点实验室,陕西西安710065 [2]西安邮电大学,陕西西安710121

出　　处：《稀有金属材料与工程》2017年第11期3217-3221,共5页Rare Metal Materials and Engineering

摘　　要：采用射频(RF)磁控溅射法在玻璃衬底上制备了SnO_2-Al_2O_3(SAO)双金属元素薄膜。通过扫描电子显微镜SEM,X射线衍射仪XRD、四探针测量,UV-IR及光致发光(PL)谱研究了衬底温度对薄膜表面形貌、晶体微结构、电学及光学特性的影响。当衬底温度升高时,SAO薄膜的晶粒尺寸增大。SEM及XRD结果显示的均质表面结构及大晶粒尺寸表明薄膜具有良好的表面形貌和结晶度。在400~800 nm的可见光范围,薄膜的透射率可达80%~90%,计算得到薄膜的带隙4.11~4.14 eV,表面电阻7.0×10~4~9.4×10~4W/。通过合理选择溅射温度,薄膜的带隙可得到增宽,表面电阻可被降低。测量还发现,所制备SAO薄膜的PL谱在UV及红光带发光,这种多晶SAO薄膜可用于透明导电氧化物(TCO)薄膜,太阳能电池窗、传感器及光发射器。SnO_2-Al_2O_3（SAO）binary thin films were prepared on slide glasses substrates by RF magnetron sputtering.The influence of the substrate temperature on the surface morphology,crystal structures,electrical and optical properties were analyzed by the scanning electron microscopy（SEM）images,X-ray diffraction（XRD）patterns,four-probe measuring,UV-IR and photoluminescence（PL）spectra.With increasing substrate temperature,the grain sizes of SAO binary films are increased.Uniform patterns and large size grains indicate a better surface morphology and crystallinity of SAO films,which are verified by SEM and XRD investigations.All the films have a high average transmittivity of^80%~90%in visible light region 400~800 nm.The calculated band gapis in a range of^4.11~4.14 eV,and the measured sheet resistances of SAO films are in a range of^7.0×10~4 to^9.4×10~4？/□.At proper sputtering temperature,the band gap can be widened,and the sheet resistances can be reduced.The PL emissions from the films in UV and red bands were also observed.These polycrystalline SAO films can be used in the application of transparent conductive oxide（TCO）films,solar cell windows,sensors,as well as lighter emitters.

关 键 词：SAO双金属元素薄膜 射频磁控溅射 电学特性 光学特性 

分 类 号：TB383.2[一般工业技术—材料科学与工程]