联烯化合物环加成反应的最新研究  

The Research in Cycloaddition Reactions of Allenic Compounds

作　　者：宫晓蕾 高文超[1] 常宏宏[1] 魏文珑[1] 李兴[1] 

机构地区：[1]太原理工大学化学化工学院生物与制药工程系,太原030024

出　　处：《化学进展》2017年第11期1331-1350,共20页Progress in Chemistry

基　　金：山西省自然科学基金项目(No.201601D011028;20130110094)资助~~

摘　　要：联烯是一类含有1,2-丙二烯结构的化合物,可与各种不饱和化合物发生多种环加成反应,由于其本身的结构和所具有的独特性质,联烯及其衍生物已经引起了国内外许多科研工作者的兴趣。本文对近几年来联烯化合物与含有各种不饱和键的化合物在不同催化剂催化作用下发生的环加成反应进行了综述,主要包括[4+2]、[3+2]、[2+2]、[1+2+2]、[2+2+2]、[4+3]和[4+2+2]等环加成反应,并对其发展方向进行了展望。Allene is a kind of compounds containing 1,2-propadiene structure. In recent years,allenes and their derivatives have attracted many researchers ＇ interest due to the unique nature. A variety of unsaturated compounds can react with allenes or their derivatives in a variety of cycloaddition reactions to prepare indole,pyridine,furan and other cyclic compounds. The recent progress in the cycloaddition reactions of allenic compounds catalyzed by different catalysts is summarized,including [4 ＋ 2],[3 ＋ 2],[2 ＋ 2],[1 ＋ 2 ＋ 2],[2 ＋ 2 ＋ 2],[4 ＋ 3],and [4 ＋ 2 ＋ 2]cycloaddition reactions,and the future development of allenic compounds is prospected.

关 键 词：联烯化合物 催化 环加成 丙二烯 不饱和键 

分 类 号：O621.3[理学—有机化学] O621.256.9[理学—化学]