甲酸锶的合成及表征  

Synthesis and characterization of strontium complex based on formic acid

作　　者：邹水香 李庆 梅舒静 陈砚美 

机构地区：[1]黄冈师范学院化学化工学院,湖北黄冈438000

出　　处：《黄冈师范学院学报》2017年第6期33-36,共4页Journal of Huanggang Normal University

基　　金：湖北省自然科学基金项目(2016CFB147);黄冈师范学院化学实验教学示范中心项目(zj201722;zj201723)

摘　　要：通过溶剂热法合成了一新的锶的配合物[Sr(HCOO)_2]n,并用X射线单晶衍射对该配合物进行了结构表征,还通过X-射线粉末衍射、红外光谱、热重分析,对配合物进行了表征。单晶衍射结果表明,配合物为三维微孔结构;热稳定性结果表明,在温度低于417℃时,配合物是稳定的,当温度高于417℃之后,配合物逐渐分解且结构坍塌。A new strontium complex [Sr（HCOO）2]n, was synthesized by solvothermal reaction method and characterized by X-ray single crystal diffraction. The complex was also characterized by X-ray powder diffraction, infrared spectra and thermogravimetric analysis. Single crystal diffraction result showed that the complex was a three-dimensional porous structure. The thermal analysis showed that the complexes were stable below 417℃, when the temperature was above 417℃, the complex decomposed and the structure collapsed.

关 键 词：碱土金属配合物 配位聚合物 锶配合物 

分 类 号：O626.21[理学—有机化学]