非贵金属催化氢酰化反应研究进展  

Advances on Hydroacylation Reaction Catalyzed by First-row Transition Metals

作　　者：李婷[1,2] 朱德萍 徐宝华 

机构地区：[1]中国科学院过程工程研究所,北京100190 [2]中国科学院大学化学与化工学院,北京100049

出　　处：《过程工程学报》2017年第6期1127-1133,共7页The Chinese Journal of Process Engineering

基　　金：国家自然科学基金资助项目(编号:U1662133)

摘　　要：近年来非贵金属因其地球丰度高、催化反应后处理方便等优点受到越来越多的关注,在某些领域取得了与贵金属相当的催化效果.本工作主要概述了非贵金属在催化C■X(X=C,O)氢酰化反应方面的研究进展,并展望了未来非贵金属催化氢酰化反应的研究方向.非贵金属催化在底物适用性、反应活性、选择性及机理研究方面还面临着更多挑战.Recently, the non-noble transition metals show an increasingly enormous application potential in homogeneous catalysis due to its relatively low cost and high abundance. And they are considered as promising catalysts which could serve as an alternative to the noble metals. The review summarizes the advances in hydroacylation, the addition of a formyl C-H bond across an unsaturated bond C X（X=C, O）, catalyzed by first-row transition metals. And challenges focusing on scope of substrates, catalytic reactivity and selectivity, even the mechanism insight into the transformation are still worthy of exploration.

关 键 词：非贵金属催化 氢酰化 C-H活化 氧化环化 

分 类 号：TQ234[化学工程—有机化工]