烯烃阴离子聚合发展60年的现状与释疑的努力  

Current Situation and Breakthrough Efforts of the Anionic Polymerization of Olefins after the Development for 60 Years

作　　者：郑安呐[1] 管涌[1] 危大福[1] 许祥[1] 陈波[1] 苏凌 

机构地区：[1]华东理工大学材料科学与工程学院上海市先进聚合物材料重点实验室超细材料制备与应用教育部重点实验室,上海200237

出　　处：《功能高分子学报》2017年第4期367-421,共55页Journal of Functional Polymers

基　　金：国家自然科学基金(29974008;50390091;50933002;51373052;51573043)

摘　　要：简述了依据阴离子聚合基本理论实施的反应挤出聚合,表述了其在工业应用领域的价值以及对阴离子聚合理论的贡献。回顾了烯烃阴离子聚合发展60年的历程,特别是近10年国内外烯烃阴离子活性聚合领域绝大部分的研究。在此基础上,列举了迄今为止烯烃阴离子聚合领域遗留的5大悬疑与2大发展瓶颈,引用本研究团队近20年来的研究,分别就阴离子聚合的释疑与突破进行了阐述。The reactive extrusion for the polymerization of olefins based on the classic theory of anionic polymerization was briefly introduced.Its application value in the industrial fields and theoretical contribution to the anionic polymerization were mainly expressed.Then,the development of olefin anionic polymerization in 60 years,especially,most of the studies in this field over the past decade,were reviewed.Based on this,the 5 pieces of suspense and 2 major bottlenecks of the development remained in the anionic polymerization of olefins were pointed out.Through citing the researches of our team in recent 20 years,the interpretation of the suspense and the breakthrough in the bottlenecks were discoursed.

关 键 词：阴离子聚合 烯烃 现状 释疑 瓶颈 

分 类 号：TQ316.32[化学工程—高聚物工业]