一种新型二茂铁席夫碱化合物的合成及其电化学性质  

Synthesis and the Electrochemical Properties of a Novel Ferrocenyl Schiff-base Compound

作　　者：宣芳 

机构地区：[1]南京晓庄学院环境科学学院,江苏南京211171

出　　处：《南京晓庄学院学报》2017年第6期5-6,51,共3页Journal of Nanjing Xiaozhuang University

基　　金：南京晓庄学院校级科研项目(2015NXY75)

摘　　要：以2-氨基-8-羟基喹啉和二茂铁甲醛为原料,设计并合成了一种新型的二茂铁席夫碱化合物,并利用紫外-可见光谱、元素分析、核磁等方法对该化合物的结构进行表征.电化学研究结果表明:该化合物的Epa,Epc,E1/2和ipc/ipa分别为0.304V,0.186V,0.245V,0.97.其氧化还原是可逆的.A Novel ferrocenoyl schiff-base compound was designed and synthesized from 2-amino-8-hydroxyquinoline and formyl-ferrocen. The structure was fully characterized by elemental analyses,1 H NMR and UV-vis. The electrochemical properties were investigated by voltammogram. The results showed that Epa,Epc,E1/2 and ipc/ipa were 0. 304 V,0. 186 V,0. 245 V,and 0. 97 respectively. The redox process of the compound was reversible.

关 键 词：合成 二茂铁 席夫碱 电化学 

分 类 号：O621.3[理学—有机化学]