三氯化铝催化异构重质松节油中β-石竹烯的研究  

Catalytic Isomerization of β-caryophyllene from Heavy Turpentine Oil by AlCl_3

作　　者：秦荣秀[1] 李桂珍[1] 梁忠云[1] 周丽珠[1] 陈海燕[1] 

机构地区：[1]广西壮族自治区林业科学研究院,南宁530002

出　　处：《广西林业科学》2017年第4期425-427,共3页Guangxi Forestry Science

基　　金：广西林科院基本科研业务费专项(林科201613号)

摘　　要：采用三氯化铝催化剂催化异构重质松节油中的β-石竹烯,考察不同反应温度、反应时间和催化剂用量对异构效果的影响。结果表明,三氯化铝催化异构重质松节油中的β-石竹烯的最佳反应条件为:催化剂用量为原料质量的5%,反应时间为3 h,反应温度为150℃。在该条件下β-石竹烯的含量由原来的13.96%降低到0.97%。通过该反应极大地降低了β-石竹烯的含量,而长叶烯含量基本保持不变。The catalytic isomerization of β-caryophyllene from heavy turpentine oil by AlCl3 was used to investigate the effects of different reaction temperatures, reaction time and amount of catalyst on isomerization. The results showed that the optimum reaction condition of catalytic isomerization of β-caryophyllene from heavy turpentine oil by AlCl3 was that the amount of catalyst was 5% of the raw material, the reaction time was 3 h and the reaction temperature was 150℃. Under this condition, the content of the β-caryophyllene decreased from 13.96% to 0.97%. By this reaction, the content of β-caryophyllene was greatly reduced, while the content of longifolene remained unchanged.

关 键 词：重质松节油 异构反应 β-石竹烯 三氯化铝 

分 类 号：TQ351[化学工程]