氟里昂替代品氟代烃的合成:从催化反应原理到工程化  

Manufacture of hydrofluorocarbons and hydrofluoroolefins as the CFCs-alternatives: from fundamental of catalytic reaction to commercialization

作　　者：张伟[1] 毛伟[1] 王博[1] 曾纪珺[1] 杨建明[1] 吕剑[1] 

机构地区：[1]氟氮化工资源高效开发与利用国家重点实验室西安近代化学研究所,西安710065

出　　处：《中国科学：化学》2017年第11期1312-1325,共14页SCIENTIA SINICA Chimica

基　　金：陕西省重点科技创新团队计划(编号:2015KCT-08);陕西省自然科学基础研究计划(编号:2017ZDJC-29)资助项目

摘　　要：氟代烃包括氢氟烃和氢氟烯烃,是臭氧损耗物质氟里昂的环保替代物,其催化合成技术的开发及应用是人类社会保护臭氧层、应对气候变化、履行国际环境公约的技术途径之一.本文总结了西安近代化学研究所近30年在催化合成氟代烃领域的技术发展,重点阐述了从催化合成反应原理、催化剂设计与制备、工艺技术集成等基础研究到工程化应用的研究现状,介绍了系列成套氟代烃合成技术的工业化应用情况,指出了我国未来氟代烃合成技术和氟化工产业的发展方向.Fluorohydrocarbons including hydrofluorocarbons and hydrofluoroolefins are environment-friendly replacements for chlorofluorocarbons, one kind of ozone-depleting substances. The development and application of catalytic synthesis technologies for fluorohydrocarbon have become an important approach to protect ozone layer, to response climatic change and to fulfill the international environmental conventions. In this paper, the progress on catalytic synthesis technologies for fluorohydrocarbon was summarized on the basis of thirty year＇s research of Xi＇an Modern Chemistry Research Institute. As the core of synthesis for fluorohydrocarbon, the recent progress of gas-phase catalytic fluorination is reviewed from fundamental research to engineering application, such as reaction mechanism, catalyst preparation, and integration of synthesis technologies. The relative technologies for commercialization and the future technological progress in this field are also briefly analyzed and discussed.

关 键 词：氟里昂 氟代烃 气相氟化 HF 固体酸 金属氟化物 

分 类 号：TQ213[化学工程—有机化工] TQ426